【摘要】 以2,4,6-三甲基苯甲酸和5,5′-二甲基-2,2′-联吡啶为配体,采用溶剂热合成法,制备出双核分子结构配合物[La（L）₃（L′）]₂（L=2,4,6-三甲基苯甲酸根,L′=5,5′-二甲基-2,2′-联吡啶）.晶体结构表明该配合物属于三斜晶系,Pī空间群,配合物分子通过配体分子之间微弱的π-π堆积作用分别形成一维链状和二维面状结构.TG-DTG/DSC研究结果表明该配合物具有一定的热稳定性,讨论了配合物的热稳定性和结构之间的构效关系.采用非线性等转化率积分法（NL-INT）和Starink法得到配合物第1步热分解过程的活化能与转化率的变化关系,计算了该步热分解反应的表观活化能.更多还原

【Abstract】 A binuclear structure[La（L）₃（L′）]₂（L=2,4,6-trimethylbenzoate,L′=5,5′-dimethyl-2,2′-bipyridine） was synthesized by using 2,4,6-trimethylbenzoic acid and 5,5′-dimethyl-2,2′-bipyridine as ligands,through sohent thermal methods.Crystal structure showed that the complex belongs to triclinic system and P ī space group.The prepared complex consists of one-dimensional chain and two-dimensional planar structure.Through the weak π-π stacking among ligand molecules,respectively.TG-DTG/DSC results showed that the complex has a fairwell degree of thermal stability.The structure-activity relationship is discussed.The nonlinear equal conversion integration method（Nl-INT） and Starink method were used to find out the relationship between activation energy of the first thermal decomposition process and conversion rate,and the average activation energy of the first thermal decomposition reaction was obtained.更多还原