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LiCoO2:获诺贝尔奖的锂离子电池正极材料还有多少潜力

LiCoO2:How much potential is there in Nobel Prize related cathode material for Li ion batteries

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【作者】 夏立爽谢召军沈恋周震

【Author】 XIA Li-shuang;XIE Zhao-jun;SHEN Lian;ZHOU Zhen;Institute of New Energy Material Chemistry,School of Materials Science and Engineering,Nankai University;Tianjin Enterprise Key Laboratory of Key Materials and Technology for Solid State Batteries;

【通讯作者】 周震;

【机构】 南开大学材料科学与工程学院新能源材料化学研究所天津市固态电池关键材料与技术企业重点实验室

【摘要】 作为最早实现商业化的锂离子电池正极材料,钴酸锂(LiCoO2)一直是学术界和产业界关注的重点。目前以LiCoO2为正极的商用锂离子电池大部分是为小型电子器件进行供能,限制其广泛应用的主要因素是能量密度和安全性能。随着社会的发展,人们在智能电子设备、便携工具和电动汽车等方面的需求越来越高,对提供能量的电池提出了更高的要求。为了实现LiCoO2正极材料的更广泛应用,需要不断优化其性能,同时还需要考虑安全性、稳定性和价格等其他因素。因此,不仅要研究LiCoO2本征性质,还要从整个电池体系考虑,揭示与其匹配的电解液和电池构造等方面的因素。以更广泛的商业化应用为目的,从LiCoO2材料本身入手,总结其近几年的研究进展,对LiCoO2的性能优化进行了着重介绍,并对其未来的发展进行了展望。

【Abstract】 As the earliest commercialized cathode material for lithium-ion batteries,LiCoO2 has been the focus of attention for a long time.At present,most commercial Li ion batteries with LiCoO2 as cathodes supply energy for small electronic devices.The main factors limiting their applications are energy density and safety concern.With the progress of society,people have growing demands for intelligent electronic devices,portable tools,electric vehicles,etc.,which have put forward higher requirements for batteries.In order to realize the application of LiCoO2 to wider fields,it is necessary to continuously optimize their performance,and at the same time,other factors also need to be considered,such as safety,stability,and price.Therefore,not only the intrinsic properties of LiCoO2,but also the entire battery system should be considered,especially the electrolyte and battery structure.For the purpose of wider commercial applications,started with LiCoO2 itself,the research progress was summarized,the performance optimization was mainly introduced,and future development was looking forward.

【关键词】 钴酸锂锂离子电池改性能量密度
【Key words】 LiCoO2lithium-ion batteriesmodificationenergy density
【基金】 天津市自然科学基金项目(19JCTPJC47300)
  • 【文献出处】 电源技术 ,Chinese Journal of Power Sources , 编辑部邮箱 ,2020年10期
  • 【分类号】TM912
  • 【被引频次】10
  • 【下载频次】776
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