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排硫硫杆菌净化处理沼气中H2S实验研究

Removal of H2S from Biogas by Tiobacillus thioparus immobilized on Granular Active Carbon

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【作者】 许海朋李岩牧辉金付强华栋梁张晓东

【Author】 XU Hai-peng;LI Yan;MU Hui;JIN Fu-qiang;HUA Dong-liang;ZHANG Xiao-dong;School of Environment Science and Engineering,Tianjin University;Energy Research Institute of Shandong Academy of Sciences;

【通讯作者】 张晓东;

【机构】 天津大学环境科学与工程学院山东省科学院能源研究所

【摘要】 文章以排硫硫杆菌(Tiobacillus thioparus)作为接种菌株,实验了活性炭填料生物滴滤塔对沼气中H2S的去除性能,研究了进气H2S浓度、气体停留时间等参数对生物滴滤塔去除沼气中H2S性能的影响。结果表明,以球状活性炭为填料,采用排硫硫杆菌接种生物滴滤塔处理含H2S沼气,挂膜速度快,系统运行稳定且脱硫效率高。固定进气H2S浓度1000 ppm,停留时间大于29 s时,H2S去除率可以达到95%以上。动力学分析表明,生物降解一级反应动力学方程能够较好地与实验数据吻合,最大H2S去除负荷为588.02 g·m-3h-1。随着实验的进行,填料塔的压力降会因为生物膜的生长和单质硫的积累逐渐增加,严重时导致气体完全堵塞,需要进行鼓泡反冲以除去积累的单质硫。

【Abstract】 In this paper, a Biotrickling filter system with Tiobacillus thioparus immobilized on granular active carbon as packing materials was used to eliminate H2S from biogas.The effect of influent H2S concentration, gas retention time on the H2S removal efficiency were investigated. It was found that the biotrickling filter system showed high bacteria adsorption capacity and high H2S removal capacity. The removal efficiency was above 95% at influent H2S concentration of 1000 ppm when the retention time was more than 29 s. The kinetic analysis showed that the maximum removal capacity of the system were 588.02 g·m-3h-1. The biotrickling filter need to be back washed when the bed pressure drop was too high due to the overgrowth of bacteria and sulfur accumulation.

【基金】 山东省重点研发计划(2016GSF117037);山东省科技发展计划项目(2017GSF17117)
  • 【分类号】X71
  • 【被引频次】2
  • 【下载频次】174
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