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BiOBr/TiO2/MIL-125(Ti)光催化还原硝酸盐的研究

The Study of Photocatalytic Reduction of Nitrate by BiOBr/TiO2/MIL-125(Ti)

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【作者】 祁昕马国强赵洁李朝阳耿直杨霞

【Author】 Qi Xin;Ma Guoqiang;Zhao Jie;Li Zhaoyang;Geng Zhi;Yang Xia;School of Environment, Northeast Normal University;Shenzhen Aerospace Smart City System Technology Co., Ltd;

【通讯作者】 杨霞;

【机构】 东北师范大学环境学院深圳航天智慧城市系统技术研究院有限公司

【摘要】 通过水热法制备了BiOBr/TiO2/MIL-125(Ti)光催化材料,采用TEM、XRD、UV-vis DRS等表征手段对催化剂的形貌、结构、光学性能等性质进行分析,并研究其在紫外光照射下对硝酸盐的转化率和氮气选择性.结果表明,复合材料0.5%BiOBr/TiO2/MIL-125(Ti)在365 nm紫外光下照射30 min后硝酸盐转化率达到88.94%,氮气选择性达到97.11%,明显高于BiOBr和MIL-125(Ti).文中对光催化还原活性提高的原因进行了细致分析.

【Abstract】 BiOBr/Ti O2/MIL-125(Ti) photocatalytic materials were prepared by hydrothermal method. The morphologies, structures and optical properties of the catalysts were analyzed by TEM, XRD and UV-vis DRS.The photocatalytic reduction ability was evaluated by the removal of nitrate. After 30 min UV light(365 nm)irradiation, the nitrate conversion rate reached to 88.94%, and the nitrogen selectivity up to 97.11% over 0.5%BiOBr/TiO2/MIL-125(Ti). The results indicated the nanocomposite exhibited significant improvement of nitrate removal efficiency than that of BiOBr and MIL-125(Ti). The reasons for the improvement were discussed in detail.

【基金】 中央高校基本科研专项资金(2412018ZD016);吉林省教育厅项目(JJKH20180021KJ)
  • 【文献出处】 伊犁师范学院学报(自然科学版) ,Journal of Yili Normal University(Natural Science Edition) , 编辑部邮箱 ,2019年01期
  • 【分类号】X703;O643.36;O644.1
  • 【被引频次】2
  • 【下载频次】222
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