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含钪7N01铝合金中Al3(Sc,Zr,Ti)相的析出及其作用机制

The Precipitation and Functional Mechanism of Al3( Sc,Zr,Ti) Phase in 7N01 Aluminum Alloy with Sc Addition

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【作者】 李召明姜海昌王昀立张舵闫德胜戎利建

【Author】 LI Zhaoming;JIANG Haichang;WANG Yunli;ZHANG Duo;YAN Desheng;RONG Lijian;CAS Key Laboratory of Nuclear Materials and Safety Assessment,Institute of Metal Research,Chinese Academy of Sciences;

【通讯作者】 姜海昌;

【机构】 中国科学院金属研究所核材料安全与评价重点实验室

【摘要】 钪是铝合金中常见的添加元素,但关于钪在铝合金中的作用机制研究还不够深入。通过电阻炉熔炼方法制备了传统7N01铝合金与新型含钪7N01铝合金,经均匀化处理后将合金热挤压成板材并进行双级人工时效处理。采用电子背散射衍射(EBSD)和透射电镜(TEM)对比分析了传统7N01铝合金与新型含钪7N01铝合金的微观组织,对时效态热挤压板材力学性能进行了表征,并分析了合金强化的作用机制。结果表明:经470℃/24 h均匀化处理后,传统7N01铝合金中析出了少量的纳米Al3(Zr,Ti)相,而含钪7N01铝合金中析出了大量纳米Al3(Sc,Zr,Ti)相。这种高密度、与基体保持共格的Al3(Sc,Zr,Ti)相对晶界迁移的钉扎效果显著,明显提升了再结晶形核的临界亚晶尺寸,抑制了热挤压过程中的动态再结晶,使含钪7N01铝合金几乎由完全的纤维结构组成。同时,含钪7N01铝合金的抗拉强度和屈服强度分别较传统7N01铝合金提高了10. 7%和13. 3%。计算结果表明,添加钪引起7N01铝合金的细晶强化和弥散强化效果分别为7和57 MPa,强化效果主要来源于Al3(Sc,Zr,Ti)相的弥散强化。

【Abstract】 Sc is a common additive element in aluminum alloys,while the functional mechanism of Sc in aluminum alloys is not completely understood. The traditional 7 N01 aluminum alloy and novel Sc modified 7 N01 aluminum alloy were prepared by electrical resistance furnace melting. After homogenization treatment,two kinds of 7 N01 alloys were hot extruded into plates,then exposed to two-stage artificial aging. Microstructures were comparatively analyzed by electron backscatter diffraction( EBSD) and transmission electron microscopy( TEM). The mechanical properties of aged hot-extruded plates were measured by electronic universal testing machine. Meanwhile,the functional mechanism to strengthen the alloy was analyzed. The results show that a small number of nanometer-sized Zr,Ti phases are precipitated in traditional 7 N01 aluminum alloy,while a large amount of nanometer-sized Al3( Sc,Zr,Ti) phases exist in 7 N01 aluminum alloy with 0. 12 wt% Sc after homogenization treatment at 470 ℃ for 24 h. The high-density Al3( Sc,Zr,Ti) phases which are coherent with matrix have a significant pinning effect on the migration of grain boundaries. It obviously improves the critical subgrain size for recrystallization nucleating.Also,the dynamic recrystallization in the hot extruding process is effectively inhibited. As a result,7 N01 aluminum alloy with0. 12 wt% Sc is almost constitutive of full fiber-like structure. At the same time,the tensile strength and yield strength of 7 N01 aluminum alloy with 0. 12 wt% Sc are 10. 7% and 13. 3% higher than those of traditional 7 N01 aluminum alloy. The calculated results indicate that fine-grain strengthening and dispersion strengthening caused by Sc addition are 7 and 57 MPa,respectively. The strengthening effect is mainly derived from dispersion strengthening of Al3( Sc,Zr,Ti) phases.

【基金】 国家重点研发计划项目(2016YFB1200602)
  • 【文献出处】 中国材料进展 ,Materials China , 编辑部邮箱 ,2019年08期
  • 【分类号】TG146.21
  • 【被引频次】8
  • 【下载频次】294
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