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流化床制备包衣尿素微球的工艺研究

Study on process of preparation of coated urea microspheres by fluidized bed

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【作者】 周建军汤建伟化全县王保明刘丽刘咏

【Author】 Zhou Jianjun;Tang Jianwei;Hua Quanxian;Wang Baoming;Liu Li;Liu Yong;School of Chemical Engineering and Energy,Zhengzhou University,National Centre of Research & Popularization on Calcium,Magnesium,Phosphate and Compound Fertilizer Technology;

【通讯作者】 刘咏;

【机构】 郑州大学化工与能源学院国家钙镁磷复合肥技术研究推广中心

【摘要】 尿素作为常用肥料之一,由于其高水溶性和过量使用易导致土壤板结和地下水污染等环境问题。利用流化床包衣技术制备缓释包膜尿素可以有效缓解上述问题。实验以明胶溶液为壁材,微粉硅胶为抗粘剂,甘油为塑化剂,戊二醛为交联剂,使用流化床包衣法制备包膜尿素。通过单因素实验考察了壁材浓度、抗粘剂用量、塑化剂用量和交联剂浓度对包膜效果的影响,并对所得产品进行了红外光谱分析和缓释性分析。最优工艺条件为:壁材质量浓度为0.05 g/m L、抗粘剂用量为10 g、塑化剂用量(质量分数)为50%、交联剂质量浓度为0.05 g/m L。

【Abstract】 As a commonly used fertilizer,urea has lead to soil compaction and groundwater pollution due to its high watersolubility and overuse.The preparation of sustained-release coated urea by fluidized bed coating technology can effectively alleviate the above problems.the coated urea was prepared by a fluid-bed coating process,using gelatin solution as film-forming material,micro-silica gel as anti-adhesive agent,glycerin as plasticizer,and glutaraldehyde as cross-linking agent respectively.The effects of wall concentration,anti-sticking agent dosage,plasticizer dosage and crosslinking agent concentration on the coating quality were investigated by single factor experiment,and the infrared spectroscopy and sustained release analysis were carried out for the obtained products.The optimum process conditions were:wall mass concentration of 0.05 g/m L,anti-adhesive agent dosage of 10 g,plasticizer dosage(mass fraction) of 50%,and cross-linking agent mass concentration of 0.05 g/m L.

【关键词】 流化床明胶包膜尿素缓释性
【Key words】 fluidized bedgelatincoated ureaslow-release
【基金】 国家重点研发计划项目(2016YFD0300805);河南省教育厅自然科学研究计划项目(2010A530007);河南省高等学校重点科研项目(15A530012)
  • 【文献出处】 无机盐工业 ,Inorganic Chemicals Industry , 编辑部邮箱 ,2019年04期
  • 【分类号】TQ441.41
  • 【下载频次】245
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