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不同成分体系无取向电工钢中夹杂物和析出物对比
Comparison of inclusions and precipitates in different grade non-oriented electrical steels
【摘要】 采用ASPEX自动扫描电镜和场发射扫描电镜,分析了不同铝、硅质量分数的无取向电工钢中的夹杂物和析出物的种类和形貌特征。采用FactSage热力学软件对夹杂物和析出物的形成进行了热力学分析。随着无取向电工钢中铝质量分数增加,氧化物类型转变规律为SiO2-Al2O3-MnO→Al2O3→MgO·Al2O3。对于铝脱氧无取向电工钢,氮化物类型为多边形的AlN。钢中铝质量分数和AlN的平均尺寸之间符合以下公式:{d}μm=3.75·[%Al]-0.57。随着铝质量分数增加,对耐火材料的侵蚀逐渐增强,钢中的镁质量分数逐渐增加。随着无取向电工钢中镁质量分数增加和硫含量降低,硫化物的转变规律为:(Mn,Cu)S→(Mn,Mg)S→MgS。
【Abstract】 In the current study,automatic scanning electron microscope and field emission scanning electron microscope were employed to analyze types and morphologies of inclusions and precipitates in non-oriented electrical steels.A thermodynamic software FactSage was conducted to analyze the inclusion formation behavior.With the increase of aluminum content,oxide inclusions changed with the the sequence of SiO2-Al2O3-MnO→Al2O3→MgO·Al2O3.For Al-deoxidized non-oriented electrical steels,angular AlN was the dominative nitride.Besides,the relationship between the average size of AlN and Al content was {d}μm=3.75·[%Al]-0.57.The content of Mg increased with the increasing Al content.With the increase of magnesium content and the decrease of sulfur,sulfides changed with the sequence of(Mn,Cu)S→(Mn,Mg)S→MgS.
- 【文献出处】 电工钢 ,Electrical Steel , 编辑部邮箱 ,2019年01期
- 【分类号】TG142.1
- 【被引频次】2
- 【下载频次】97