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不同成分体系无取向电工钢中夹杂物和析出物对比

Comparison of inclusions and precipitates in different grade non-oriented electrical steels

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【作者】 任强程林胡志远张立峰

【Author】 REN Qiang;CHENG Lin;HU Zhiyuan;ZHANG Lifeng;School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing;Shougang Zhixin Qian’an Electromagnetic Material Co.,Ltd.,Department of Product Development;

【通讯作者】 张立峰;

【机构】 北京科技大学冶金与生态工程学院首钢智新迁安电磁材料有限公司产品研发部

【摘要】 采用ASPEX自动扫描电镜和场发射扫描电镜,分析了不同铝、硅质量分数的无取向电工钢中的夹杂物和析出物的种类和形貌特征。采用FactSage热力学软件对夹杂物和析出物的形成进行了热力学分析。随着无取向电工钢中铝质量分数增加,氧化物类型转变规律为SiO2-Al2O3-MnO→Al2O3→MgO·Al2O3。对于铝脱氧无取向电工钢,氮化物类型为多边形的AlN。钢中铝质量分数和AlN的平均尺寸之间符合以下公式:{d}μm=3.75·[%Al]-0.57。随着铝质量分数增加,对耐火材料的侵蚀逐渐增强,钢中的镁质量分数逐渐增加。随着无取向电工钢中镁质量分数增加和硫含量降低,硫化物的转变规律为:(Mn,Cu)S→(Mn,Mg)S→MgS。

【Abstract】 In the current study,automatic scanning electron microscope and field emission scanning electron microscope were employed to analyze types and morphologies of inclusions and precipitates in non-oriented electrical steels.A thermodynamic software FactSage was conducted to analyze the inclusion formation behavior.With the increase of aluminum content,oxide inclusions changed with the the sequence of SiO2-Al2O3-MnO→Al2O3→MgO·Al2O3.For Al-deoxidized non-oriented electrical steels,angular AlN was the dominative nitride.Besides,the relationship between the average size of AlN and Al content was {d}μm=3.75·[%Al]-0.57.The content of Mg increased with the increasing Al content.With the increase of magnesium content and the decrease of sulfur,sulfides changed with the sequence of(Mn,Cu)S→(Mn,Mg)S→MgS.

  • 【分类号】TG142.1
  • 【被引频次】2
  • 【下载频次】97
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