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海水中主要无机阴离子对针铁矿吸附磷的影响

Effect of Main Inorganic Anions in Seawater on Phosphorus Adsorption by Goethite

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【作者】 沙恩都合什·努尔哈力叶尔加那提·乌鲁乎盘胡亚楠赵艳锋

【Author】 SHAENDUHESHI·Nuerhali;YEERJIANATI·Wuluhupan;HU Ya-nan;ZHAO Yan-feng;College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University;School of Mining Engineering, Liaoning Shihua University;

【通讯作者】 赵艳锋;

【机构】 辽宁石油化工大学化学化工与环境学部辽宁石油化工大学矿业工程学院

【摘要】 采用水解中和法制备了针铁矿,研究了海水中的无机阴离子Cl-、Br-、F-、SO42-和HCO3-对针铁矿吸附磷的影响。结果表明:当存在SO42-、Cl-、Br-和F-时,针铁矿吸附低浓度磷酸盐受到抑制,吸附高浓度磷酸盐时得到促进;而HCO3-对针铁矿吸附磷有着很强的抑制能力;全部组分的主要无机阴离子共同存在时,针铁矿吸附磷受到抑制,酸性条件下的吸附量高于碱性条件。

【Abstract】 Goethite was prepared by hydrolysis and neutralization method. And then the effect of inorganic anions Cl-, Br-, F-, SO42-and HCO3-in seawater on phosphorus adsorption by the goethite was studied. The results showed that, when SO42-, Cl-, Br-and F-existed, goethite adsorbing low concentration phosphate was inhibited, adsorbing high concentration phosphate was promoted; HCO3-had strong inhibitory effect on the adsorption of phosphorus by goethite; when the main inorganic anionic electrolytes coexisted, phosphorus adsorption by goethite was inhibited, the adsorption amount under acidic conditions was higher than that under alkaline conditions.

【关键词】 针铁矿海水磷酸盐无机阴离子
【Key words】 GoethiteSeawaterPhosphateInorganic anion
  • 【文献出处】 当代化工 ,Contemporary Chemical Industry , 编辑部邮箱 ,2019年09期
  • 【分类号】X703
  • 【下载频次】132
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