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1,6-己二醇制备工艺进展

Review on the preparation process of 1,6-hexanediol

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【作者】 王新龙王晓东雷小楠卢杰韩路长

【Author】 Wang Xinlong;Wang Xiaodong;Lei Xiaonan;Lu Jie;Han Luchang;Sinopec Baling Petrochemical Company;Chemical Engineering Institute,Xiangtan Unversity;

【通讯作者】 韩路长;

【机构】 中国石化巴陵石化分公司湘潭大学化工学院

【摘要】 综述了1,6-己二醇的生产工艺,主要包括传统的以石油基为原料和新兴的以生物基为原料的工艺路线。目前,工业上仍采用以石油基原料为主的工艺路线,存在环境污染、能耗偏高、产物选择性偏低或产物纯度不高等问题。烯烃直接光催化水合制备1,6-己二醇的方法具有清洁、能耗低、副产物少等特点,但缺乏高效的水合催化剂。以生物基为原料制备1,6-己二醇具有环境污染小、原料可再生的特点,有良好的发展前景。

【Abstract】 In this paper,the production process of 1,6-hexanediol is reviewed,including the traditional preparation routes with petroleum-based materials and with new biological materials. At present,the preparation routes of using petroleum-based raw materials are still applied in industry,most of which pollute the environment,consume more energy,and have low selectivity to the products or produce low purity products. Preparation of 1,6-hexanediol by direct photo-catalytic hydration of olefins is characterized by cleanliness,low energy consumption and fewer by-products.However,there is a lack of efficient hydration catalysts. The preparation method of 1,6-hexanediol with bio-based materials has the characteristics of less environmental pollution and renewable raw materials,and has good prospects for development.

【基金】 湖南省教育厅重点项目(18A076)
  • 【文献出处】 石油化工 ,Petrochemical Technology , 编辑部邮箱 ,2019年05期
  • 【分类号】TQ223.162
  • 【被引频次】7
  • 【下载频次】814
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