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催化氧化耦合超重力技术脱除NO_x的研究

Removal of NO_x by catalytic oxidation coupled with high gravity technology

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【作者】 吴博段开娇唐光阳贾丽娟高冀芸彭金辉刘天成

【Author】 WU Bo;DUAN Kai-jiao;TANG Guang-yang;JIA Li-juan;GAO Ji-yun;PENG Jin-hui;LIU Tian-cheng;School of Chemistry and Environment,Yunnan Minzu University;Key Laboratory of Unconventional Metallurgy,Ministry of Education;

【通讯作者】 段开娇;刘天成;

【机构】 云南民族大学化学与环境学院非常规冶金教育部重点实验室

【摘要】 用Mn Fe Ox气相催化氧化NO,在旋转填充床中以Na OH溶液吸收脱除NO_x。考察模拟烟气中NO的转化率、进口体积分数、吸收液循环使用时间对NO_x脱除率影响,监测了吸收液循环使用时间420 min内的p H值及离子成分。结果表明,NO转化率55. 17%时,NO_x脱除率达93. 42%; NO进口体积分数提升,使NO_x的脱除率先上升后下降;Na OH吸收液循环使用420 min内,NO_x脱除率在90. 8%以上,反应产物为NO-2及少量NO-3,p H值12. 68。

【Abstract】 Mn Fe Oxwas used to catalytic oxidation of NO in gas phase and removes NO_xby Na OH solution in a rotating packed bed. The removal efficiency of NO_xwas investigated under various operating conditions including the conversion rate of NO,inlet NO volume fraction and cycling time of the absorption solution in the simulated flue gas. Also,the p H value and ionic composition of the absorption solution were tested at the cycling time of 420 min. The results indicated that the removal efficiency of NO_xis 93. 42% when the conversion rate of NO is 55. 17%. Additionally,NO_xremoval efficiency first increased and then decreased with increasing inlet NO volume fraction. Moreover,the removal efficiency of NO_xwas stable above 90. 8% after420 min of Na OH absorption solution and the main component of the absorption solution was NO-2,the small amount of NO-3 and the p H value of the absorption solution was 12. 68.

【基金】 国家自然科学基金(51568068);云南省应用基础研究基金(2017FD119);云南省教育厅科学研究基金(2016ZZX127)
  • 【文献出处】 应用化工 ,Applied Chemical Industry , 编辑部邮箱 ,2019年01期
  • 【分类号】O643.32;X701
  • 【下载频次】129
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