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蒲公英多糖铁(Ⅲ)的制备

Preparation of Taraxacum Polysaccharides Iron (Ⅲ) Complex

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【作者】 姜雪莹黄亚杉张莲姬

【Author】 JIANG Xueying;HUANG Yashan;ZHANG Lianji;Department of Chemistry, College of Science, Yanbian University;Chemical National Experimental Demonstration Center, Yanbian University;

【通讯作者】 张莲姬;

【机构】 延边大学理学院化学系延边大学化学国家级实验教学示范中心

【摘要】 研究蒲公英多糖铁的制备工艺及其理化性质。将蒲公英多糖与氯化铁反应制得蒲公英多糖铁(Ⅲ),测定一般理化性质和铁含量,用红外光谱对其结构进行分析,并以蒲公英多糖铁的产率和铁含量为评价指标,通过正交试验确定其最佳制备工艺条件。结果表明,蒲公英多糖铁为无定型红棕色粉末,易溶于水,与Fe3+形成稳定的配合物,不存在游离Fe3+,在空气中可以稳定存在,蒲公英多糖铁中铁(Ⅲ)含量为22.7%。蒲公英多糖铁的最佳制备工艺条件为:蒲公英多糖与柠檬酸三钠质量比2︰1、反应温度60℃、反应液pH 8。

【Abstract】 The optimization of Taraxacum polysaccharides iron complex and its physical and chemical properties were studied Taraxacum polysaccharides was reacted with ferric chloride to obtain araxacum polysaccharides iron complex,its common physical and chemical properties and the content of Fe were measured.The structure of Taraxacum polysaccharides iron complex was identified by infrared spectroscopy.Using the iron content in Taraxacum polysaccharides iron complex and the output as the reference index,explore the factors of the best synthesis technique of Taraxacum polysaccharides iron complex by orthogonal.The result showed that Taraxacum polysaccharides iron complex was amorphous reddish-brown powder and highly soluble in water.The complex combined with Fe3+was stable without any free Fe3+at the air.The iron content of Taraxacum polysaccharide iron complex was 22.7%.The best synthesis technique of Taraxacum polysaccharides iron complex was that the mass ratio of Taraxacum polysaccharides and catalystn 2︰1,the temperature 60℃,and the pH 8.

【基金】 延边大学2018年大学生创新创业训练计划项目(项目编号:ydcxcy2018126)
  • 【分类号】O657.33;TQ461
  • 【被引频次】5
  • 【下载频次】357
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