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铜源对铜掺杂MAPbI3薄膜结构和光学性质的影响

Effect of copper source on the structure and optical properties of copper doped MAPbI3 thin films

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【作者】 杨丽丽葛欣李丹宋榕菲王策

【Author】 YANG Li-li;GE Xin;LI Dan;SONG Rong-fei;WANG Ce;Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education,Jilin Normal University;

【机构】 吉林师范大学功能材料物理与化学教育部重点实验室

【摘要】 有机-无机杂化钙钛矿(MAPbI3)材料已成为光电器件领域的先进材料,但铅元素的存在带来的环境污染问题严重影响钙钛矿材料的实际应用.以无毒性金属元素部分取代铅元素是推进其应用进程的途径之一.选用氯化铜和醋酸铜作为铜元素掺杂源,利用一步法合成铜掺杂钙钛矿薄膜,研究不同铜源对MAPbI3薄膜成膜质量和光学性质的影响,并揭示影响机制.

【Abstract】 Organic-inorganic hybrid perovskite(MAPbI3) materials have become the advanced materials in the field of optoelectronic devices.However,the environmental pollution caused by the presence of lead elements seriously affects the practical application of perovskite materials.The partial replacement using with the non-toxic metal elements is one of the ways to prompt its application process.In this work,cupric chloride and copper acetate were selected as the doping sources for copper.The copper-doped perovskite films were synthesized by one-step method.The effects of different copper sources on the quality and optical properties of MAPbI3 films were studied,and the influencing mechanism was also revealed.

【基金】 国家自然科学基金项目(61775081)
  • 【文献出处】 吉林师范大学学报(自然科学版) ,Jilin Normal University Journal(Natural Science Edition) , 编辑部邮箱 ,2019年04期
  • 【分类号】TB383.2;TM914.4
  • 【下载频次】86
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