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CaO-MgO-Al2O3-Fe2O3-B2O3-SiO2系微晶釉的制备

Preparation of Microcrystalline Glazes of CaO-MgO-Al2O3-Fe2O3-B2O3-SiO2 System

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【作者】 吴玉敏王江博王留召周爱国

【Author】 WU Yu-min;WANG Jiang-bo;WANG Liu-zhao;ZHOU Ai-guo;School of Materials Science and Engineering,Henan Polytechnic University;Wuhan Sanyuan Special Building Materials Co.,Ltd.;

【机构】 河南理工大学材料科学与工程学院武汉三源特种建材有限责任公司

【摘要】 通过引入B2O3以降低烧成温度,利用赤泥中的Fe2O3为着色剂,在1150℃左右低温烧成制备了CaO-MgOAl2O3-Fe2O3-B2O3-SiO2系微晶釉。赤泥的加入量为20%左右时,釉面具有良好的装饰效果和显微硬度。利用XRD、SEM研究了釉的物相及显微组织。结果表明,釉中析出的微晶是普通辉石,微晶的含量随MgO及CaO的含量增加而增加,而提高Al203含量则抑制微晶的析出。

【Abstract】 The CaO-MgO-Al2 O3-Fe2 O3-B2 O3-SiO2 system microcrystalline glazes were prepared at 1150 ℃ by using B2 O3 as fluxing agent and Fe2 O3 in red mud as the color agent. When the content of red mud is about 20%,the prepared glaze surface has good decorative effect and microhardness. The microstructure of glaze layer was investigated by X-ray diffraction and scanning electron microscopy. From the results,it was shown that the main phase of the microcrystalline glaze was augite. The content of crystalline phase increased with the increasing of MgO and CaO contents. However,with the increasing of Al2 O3 content,the content of crystalline phase decreased.

【关键词】 微晶釉低温烧成赤泥辉石茶叶末
【Key words】 microcrystalline glazelow temperatuer firingred mudaugitetea dust
【基金】 国家自然科学基金(51772077);河南省高校科技创新团队(19IRTSTHN027)
  • 【文献出处】 人工晶体学报 ,Journal of Synthetic Crystals , 编辑部邮箱 ,2019年07期
  • 【分类号】TQ174.43
  • 【下载频次】180
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