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Facile Synthesis, Morphologies and Gas Sensing Properties of CuO Powder

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【作者】 黄旭荆卫东汤德平俞瀚吴啸郑兴华

【Author】 HUANG Xu;JING Wei-Dong;TANG De-Ping;YU Han;WU Xiao;ZHENG Xing-Hua;Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University;School of Mechanical & Automotive Engineering, Fujian University of Technology;College of Zijin Mining, Fuzhou University;

【通讯作者】 郑兴华;

【机构】 Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou UniversitySchool of Mechanical & Automotive Engineering, Fujian University of TechnologyCollege of Zijin Mining, Fuzhou University

【摘要】 CuO powder with microspheres, submicron sheets had been synthesized only from CuSO4 and Na2CO3 aqueous solutions by a facile route. Significant effects of initial droplet size of CuSO4 aqueous solution were observed on particle size, morphology and gas sensitivity of CuO. The morphologies of CuO powder varied from microspheres to submicron sheets with the introduction method of CuSO4 to Na2CO3 aqueous solutions. Based on the characterized structure and morphology, a possible formation mechanism of CuO had been proposed. High gas sensitivity to ethanol was obtained for the CuO microspheres synthesized by spray method, which exhibited the response sensitivity of 3.25 to ethanol with the concentration of 300 ppm at 250 ℃. It suggests that the facile route is promising to the batch synthesis of CuO powder with good gas sensing properties.

【Abstract】 CuO powder with microspheres, submicron sheets had been synthesized only from CuSO4 and Na2CO3 aqueous solutions by a facile route. Significant effects of initial droplet size of CuSO4 aqueous solution were observed on particle size, morphology and gas sensitivity of CuO. The morphologies of CuO powder varied from microspheres to submicron sheets with the introduction method of CuSO4 to Na2CO3 aqueous solutions. Based on the characterized structure and morphology, a possible formation mechanism of CuO had been proposed. High gas sensitivity to ethanol was obtained for the CuO microspheres synthesized by spray method, which exhibited the response sensitivity of 3.25 to ethanol with the concentration of 300 ppm at 250 ℃. It suggests that the facile route is promising to the batch synthesis of CuO powder with good gas sensing properties.

【关键词】 CuO microspheresgas sensorspray
【Key words】 CuO microspheresgas sensorspray
【基金】 Supported by the National Natural Science Foundation of China(No.51602055)
  • 【文献出处】 Chinese Journal of Structural Chemistry ,结构化学(英文版) , 编辑部邮箱 ,2019年11期
  • 【分类号】TQ131.21
  • 【下载频次】43
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