节点文献

依溶解度系数制备高导电石墨烯/橡胶复合物

Preparation of highly conductive graphene/natural rubber composites based on solubility parameters

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 宋成芝谢华高寒阳刘海军胡国新胡宇辰薛晨

【Author】 SONG Cheng-zhi;XIE Hua;GAO Han-yang;LIU Hai-jun;HU Guo-xin;HU Yu-chen;XUE Chen;Shanghai Marine Diesel Engine Research Institute;School of Mechanical and Power Engineering, Shanghai Jiao Tong University;School of Mechanical Engineering, Hangzhou Dianzi University;

【通讯作者】 胡国新;

【机构】 中国船舶重工集团公司第七一一研究所上海交通大学机械与动力工程学院杭州电子科技大学机械工程学院

【摘要】 文章根据石墨烯、天然橡胶、甲苯及NMP 4种物质的汉森溶解度系数,设计出一套简便的石墨烯/天然橡胶复合材料制备方法。该方法先将石墨烯/NMP与天然橡胶/甲苯按一定比例混合,使甲苯/NMP混合溶液的溶解度系数与橡胶及石墨烯接近,使橡胶和石墨烯均能均匀地分散在混合液中;在接下来的开口搅拌过程中,随着甲苯的挥发,NMP/甲苯混合液的溶液度系数逐步向纯NMP溶液相偏离,致使橡胶分子夹带石墨烯片逐步自液体中析出而形成复合物。本方法操作简便,制备得到的复合材料导电性能优秀,石墨烯的渗透阈限在1%—1.5%。

【Abstract】 Based on the Hansen solubility parameters of graphene, natural rubber, toluene, and NMP, a simple method for preparing graphene/natural rubber composites was proposed. In this method, the graphene/NMP suspension is mixed with the rubber/toluene mixture in a certain ratio, making the solubility parameter of toluene/NMP mixture similar to that of rubber or graphene. In the next process, the mixture was stirred in an opened container. As the toluene is volatilized, the solution parameter of the mixture gradually approaches to that of the pure NMP, causing rubber molecules wrapped with graphene gradually precipitate from the liquid to form a composite. Our method is simple and convenient. The prepared composite material has a graphene penetration threshold of 1%-1.5% and excellent electrical conductivity.

【基金】 中国船舶重工集团公司科技创新项目(2017K07);国家自然科学基金资助项目(51876052)
  • 【文献出处】 化学工程 ,Chemical Engineering(China) , 编辑部邮箱 ,2019年11期
  • 【分类号】TB332
  • 【被引频次】1
  • 【下载频次】138
节点文献中: 

本文链接的文献网络图示:

本文的引文网络