【摘要】 本文用水热法合成得到一个六元瓜环（Q[6]）与一氯三水（4-吡啶甲酸）合镉（Ⅱ）配位聚合物自组装作用形成的超分子自组装体Q[6]·[Cd（H₂O）₃Cl（4-PCA）]₂·22（H₂O）。自组装体的形成源于瓜环的外壁作用,即Q[6]正电性静电势外壁与配位聚合物中4-吡啶甲酸吡啶环和配位Cl^-离子间的超分子相互作用,以及配位聚合物镉（Ⅱ）离子上配位水分子与瓜环端口羰基氧原子间的氢键作用。该自组装体对溶液中染料具有吸附作用和光催化降解的性能。更多还原

【Abstract】 In this paper,a supramolecular self-assembly{Q[6]·[Cd（H₂ O）₃Cl（4-PCA） ]₂·22 H₂O} comprising cucurbit[6]uril（ Q[6]） and a 4-pyridine carboxylic acid（ 4-PCA） and cadmium（ Ⅱ） coordination polymer was synthesized with hydrothermal method.The formation of the supramolecular self-assembly was driven by the outer surface interaction of cucurbit[n]uril,which is the supramolecular interactions between positive electro-potential of the outer surface of Q[6]with pyridine ring and Cl-anion in the coordination polymer,and hydrogen bonding interaction between water molecules and the portal carbonyl oxygens atoms of Q[6]. The self-assembly entity has the properties of adsorption and photocatalytic degradation of dyes in solution.更多还原