【摘要】 杂环化合物是有机化学的重要组成部分,关于其C-H键的活化研究一直是有机工作者的关注热点,近年来大量关于杂环化合物C-H键活化实现C-C键的交叉偶联的文献被报道,其中包括金属钯催化、金属铜的催化、其他金属催化以及无金属催化等,杂环化合物广泛存在于自然界及活化分子中,在生物体内常常扮演着重要角色。综述了近年来该领域的研究进展,期望能对更多复杂有机杂环化合物的简便合成提供参考。更多还原

【Abstract】 Heterocyclic compounds are an important part of organic chemistry. The research on the activation of CH bonds has been a hot topic of organic workers. In recent years,a large number of literatures on the cross-coupling of C-C bonds by the activation of heterocyclic compounds with C-H bonds have been reported,including metal palladium catalysis,metal copper catalysis,other metal catalysis and metal-free catalysis. Heterocyclic compounds are widely found in nature and activated molecules,and often play an important role in living organisms. Recent advances in this field were reviewed,hoping to provide a reference for the simple synthesis of more complex organic heterocyclic compounds.更多还原