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5A沸石分子筛低温变压吸附CO2/CH4实验研究

Experimental Study on CO2/CH4 Adsorption of 5A Zeolite at Low Temperature Pressure Swing

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【作者】 曾国治王睿库尔刘学武邹久朋陈淑花

【Author】 ZENG Guo-zhi;WANG Rui;Kuer;LIU Xue-wu;ZOU Jiu-peng;CHEN Shu-hua;School of Chemical Machinery and Safety,Dalian University of Technology;College of Environmental and Chemical Engineering,Dalian University;

【通讯作者】 王睿;

【机构】 大连理工大学化工机械与安全学院大连大学环境与化学工程学院

【摘要】 采用静态容积法测量5A沸石分子筛对CO2和CH4的单组份等温吸附曲线,采用低温变压测量不同实验参数对5A沸石分子筛分离CH4/CO2混合气体的能力影响。静态实验表明,CO2和CH4吸附量随温度的降低而上升,-30℃时CO2和CH4在吸附剂上的饱和吸附量最高:分别为4.94 mmol/g和3.0 mmol/g;动态试验表明,增加吸附压力会降低分离效果,减小混合气体分离系数;降低吸附温度有利于CH4/CO2分离,提高混合气体分离系数。

【Abstract】 The isothermal adsorption curves of CO2and CH4on 5A zeolite were measured by static volumetric method,the influence of different experimental parameters on the separation of CH4/CO2mixture gas from CH4/CO2was measured by low temperature pressure.The static experiment showed that the adsorption capacity of CO2and CH4on adsorbent was the highest at 30℃with the decrease of temperature:4.94 mmol/g and 3.0 mmol/g,respectively.The dynamic test showed that increasing adsorption pressure can reduce the separation efficiency and decrease the separation coefficient of mixed gas,lower the adsorption temperature is favorable to the separation of CH4/CO2and increase the separation coefficient of mixed gas.

【基金】 国家自然科学基金资助项目(21776029);大连市科技创新基金资助(2018J12GX059);大学生创新创业训练计划资助(2018101410101010119)
  • 【文献出处】 广州化工 ,Guangzhou Chemical Industry , 编辑部邮箱 ,2019年10期
  • 【分类号】TQ424.25;TE644
  • 【被引频次】9
  • 【下载频次】378
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