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解读《有机化合物命名原则-2017》——新老命名原则的比较及常见取代基的命名

Explanation of “Nomenclature of Organic Compounds-2017”: Comparison of Nomenclature Rules and Nomenclature of Common Substituent Groups

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【作者】 马宁王光伟张文勤

【Author】 MA Ning;WANG Guangwei;ZHANG Wenqin;National Demonstration Center for Experimental Chemistry & Chemical Engineering Education (Tianjin University), Department of Chemistry, School of Science, Tianjin University;

【通讯作者】 王光伟;张文勤;

【机构】 天津大学理学院化学系化学化工国家级实验教学示范中心(天津大学)

【摘要】 对中国化学会新修订的《有机化合物命名原则-2017》与《有机化学命名原则》(1980)的不同之处进行解读,对取代基命名的基本原则、取代基碳链编号的方式进行了归纳、分析,整理汇总了本科有机化学教学中常见取代基的名称,便于大家教学和交流。提出了有机化合物命名的系统化、规范化、简单化、一致化及"向后看齐"等原则,取代基碳骨架无特殊编号规定时采用基碳原子编号为1的方案,仅保留少数取代基俗名(普通名),对于甲酰基相关基团的命名提出了建议。

【Abstract】 The differences between "Nomenclature of Organic Compounds-2017" and "Nonmenclature of Organic Chemistry(1980)" issued by Chinese Chemical Society are described. The general principles and numbering methods for naming substituent groups commonly used in organic chemistry for undergraduates are analyzed and explained; the proper systematic names are recommended to benefit classroom teaching and academic communication. Moreover, the principles such as systemization, standardization, simplification, uniformization, and "looking afterward" are proposed. Some recommendations are further presented: 1) numbering the carbon skeleton of the substituent without compulsory numbering rule always begins at the point of attachment; 2) only preserving a minority of trivial names(common names); 3) naming methanoyl(formyl)-analogue groups following the name of methanoyl.

【关键词】 有机化合物命名取代基
【Key words】 Organic compoundsNomenclatureSubstituent group
  • 【文献出处】 大学化学 ,University Chemistry , 编辑部邮箱 ,2019年09期
  • 【分类号】O62-01
  • 【被引频次】8
  • 【下载频次】643
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