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高剪切反应器中有机相强化KHCO3/K2CO3溶液吸收CO2研究

Study on CO2 absorption into KHCO3/K2CO3 solution intensified by organic phase in a high shear reactor

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【作者】 冯奇王磊邵磊

【Author】 FENG Qi;WANG Lei;SHAO Lei;State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology;Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology;

【通讯作者】 邵磊;

【机构】 北京化工大学有机无机复合材料国家重点实验室北京化工大学教育部超重力工程研究中心

【摘要】 在高剪切反应器(HSR)中研究了不同有机分散相对KHCO3/K2CO3溶液吸收CO2的强化效果,并考察了有机相与有机胺溶液复配使用对CO2吸收率的影响。实验结果表明:环己烷、正庚烷对KHCO3/K2CO3溶液吸收CO2的强化效果明显,甲苯、正辛醇对KHCO3/K2CO3溶液吸收CO2则没有明显的强化效果;CO2吸收率随HSR转速的增加而增加,随气液比、温度的增加而降低;环己烷对加入二乙醇胺活化的K2CO3溶液有较为明显的强化作用,CO2吸收率最高可提高23%。与文献中不同反应器的对比表明HSR对CO2具有较高的吸收效率。

【Abstract】 The intensification effect of different organic phases on the absorption of CO2 by KHCO3/K2CO3 solution in a high shear reactor(HSR) was investigated, and the combined effect of organic phase with organic amine on CO2 absorption was also studied. The experimental results showed that cyclohexane and n-heptane exhibited significant intensification effect on the absorption of CO2 by KHCO3/K2CO3 solution, while the intensification effect of toluene and n-octanol on CO2 absorption by KHCO3/K2CO3 solution was negligible. CO2 absorption percentage increased with the increase in the rotation speed of HSR and decreased with increasing gas-liquid ratio and temperature. CO2 absorption by diethanolamine-activated K2CO3 solution was significantly enhanced by the addition of cyclohexane, with an increase of CO2 absorption percentage up to 23%. HSR demonstrated a high efficiency for CO2 absorption by a comparison with other reactors in the literature.

【基金】 国家自然科学基金(21676008)
  • 【文献出处】 北京化工大学学报(自然科学版) ,Journal of Beijing University of Chemical Technology(Natural Science Edition) , 编辑部邮箱 ,2019年01期
  • 【分类号】TQ028.14
  • 【被引频次】4
  • 【下载频次】98
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