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改性聚合物压裂液的合成及其性能
Synthesis and Properties of Modified Polymer Fracturing Fluid
【摘要】 为了提高油田压裂改造中常用水基压裂液的耐温和耐盐性能,本文以丙烯酸(AA)、丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)和季铵盐型长尾疏水单体(DS)为原料,制备了疏水改性聚合物增稠剂(AAAD)。有机硼酸盐与葡萄糖酸钠形成配合物(GS-2)为交联剂,再加入其它添加剂,AAAD通过交联反应,制备出改性聚合物压裂液。评价了该体系的流变性、黏弹性、耐温性、抗盐性和破胶性等性能。结果表明,压裂液在温度150℃、剪切速率170 s-1条件下具有良好的流变性能;在90℃,破胶剂过硫酸铵质量分数为0.01%条件下,4 h即可破胶,破胶液黏度为1.6 m Pa·s。
【Abstract】 In order to improve the temperate and salt tolerance performance of water base fracturing fluid used in fracturing and reconstruction of oil field,acrylic acid(AA),acrylamide(AM),2-acrylamide-2-methyl propane sulfonic acid(AMPS)and cationic hydrophobic long chain monomer(DS)were used as raw materials to prepare a modified hydrophobic polymer thickener(AAAD).A new fracturing fluid system was prepared using AAAD as the thickening agent,the complex of organic borates and sodium gluconate(GS-2)as the crosslinking agent.The system rheology and viscoelasticity,temperature resistance,salt resistance and gel breaking performance were evaluated.The results show that the fracturing fluid has good rheological properties at 150℃with the shear rate of 170 s-1.The gel can be broken within 4 h at 90℃and the viscosity of the gel breaking liquid is 1.6 m Pa·s when mass fraction of ammonium persulfate is 0.01%.
【Key words】 hydrophobic modified polymers; fracturing fluid; temperature resistance; rheological characteristic;
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2018年11期
- 【分类号】TE39
- 【被引频次】8
- 【下载频次】316