A variety of mono-, di-, and tri-substituted(aryl, alkyl, and/or alkenyl) isoxazoles were synthesized from readily accessible α,β-unsaturated oximes via I_2-mediated oxidative C—O bond formation. The features of this synthetic approach include no use of transition metals, simple operation, mild reaction conditions, short reaction time, and broad substrate scope.
【基金】
supported by the National Natural Science Foundation of China(Nos.81773570,81330075);
the Outstanding Young Talent Research Fund of Zhengzhou University(No.1521316004)~~
【更新日期】
2019-01-23
【分类号】
O626
【正文快照】
1 IntroductionIsoxazole is an important five-membered aromatic het-erocyclic skeleton[1] widely distributed in biologically ac-tive natural and synthetic products. Moreover, its deriva-tives are also used extensively as insecticides or fungicidesin agroch
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