Two novel Cd(Ⅱ) coordination polymers(CPs), formulated as [Cd(m-phda)(btbb)0.5]n(1) and [Cd(m-phda)(hbmb)0.5]n(2)(m-H2 phda=m-phenylenediacetic acid, btbb=1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene,hbmb=1,1′-(1,6-hexane)bis-(2-methylbenzimidazole)) have been prepared by hydrothermal reactions of the semirigid ligand m-H2 phda with Cd (Ⅱ) ions in the presence of two disparate N-heterocyclic co-ligands and further characterized by infrared spectra(IR), powder X-ray diffraction(PXRD), elemental an...
河南科技学院高层次人才科研启动项目、河南科技学院大学生创新训练计划项目、河南省博士后科研项目、河南省高等学校重点科研项目(No.16A150007)和河南科技学院标志性创新工程项目(No.2015BZ02)资助。*通信联系人。E-mail:liululiulu2012@126.com,houhongw@zzu.edu.cnTwo 3D C