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The impact of Al2O3 back interface layer on low-temperature growth of ultrathin Cu(In,Ga)Se2 solar cells

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【作者】 刘杨刘玮陈梦馨史思涵何志超巩金龙王拓周志强刘芳芳孙云徐术

【Author】 LIU Yang;LIU Wei;CHEN Meng-xin;SHI Si-han;HE Zhi-chao;GONG Jin-long;WANG Tuo;ZHOU Zhi-qiang;LIU Fang-fang;SUN Yun;XU Shu;Tianjin Key Laboratory of Thin Film Devices and Technology,Institute of Photoelectronic Thin Film Devices and Technology,Nankai University;Key Laboratory for Green Chemical Technology of Ministry of Education,Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),School of Chemical Engineering and Technology,Tianjin University;Davidson School of Chemical Engineering,Purdue University;

【通讯作者】 刘玮;

【机构】 Tianjin Key Laboratory of Thin Film Devices and Technology,Institute of Photoelectronic Thin Film Devices and Technology,Nankai UniversityKey Laboratory for Green Chemical Technology of Ministry of Education,Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),School of Chemical Engineering and Technology,Tianjin UniversityDavidson School of Chemical Engineering,Purdue University

【摘要】 With reducing the absorber layer thickness and processing temperature,the recombination at the back interface is severe,which both can result in the decrease of open-circuit voltage and fill factor.In this paper,we prepare Al2O3 by atomic layer deposition(ALD),and investigate the effect of its thickness on the performance of Cu(In,Ga)Se2(CIGS)solar cell.The device recombination activation energy(EA)is increased from 1.04 eV to 1.11 eV when the thickness of Al2O3 is varied from 0 nm to 1 nm,and the height of back barrier is decreased from 48.54 meV to 38.05 meV.An efficiency of 11.57%is achieved with 0.88-μm-thick CIGS absorber layer.

【Abstract】 With reducing the absorber layer thickness and processing temperature,the recombination at the back interface is severe,which both can result in the decrease of open-circuit voltage and fill factor.In this paper,we prepare Al2O3 by atomic layer deposition(ALD),and investigate the effect of its thickness on the performance of Cu(In,Ga)Se2(CIGS)solar cell.The device recombination activation energy(EA)is increased from 1.04 eV to 1.11 eV when the thickness of Al2O3 is varied from 0 nm to 1 nm,and the height of back barrier is decreased from 48.54 meV to 38.05 meV.An efficiency of 11.57%is achieved with 0.88-μm-thick CIGS absorber layer.

【关键词】 CIGSabsorberrecombinationthickvariedpreparepreferredannealeddisplayedinsert
【基金】 supported by the National Natural Science Foundation of China(Nos.61774089 and 61504067);the Yang Fan Innovative & Entrepreneurial Research Team Project(No.2014YT02N037)
  • 【文献出处】 Optoelectronics Letters ,光电子快报(英文版) , 编辑部邮箱 ,2018年05期
  • 【分类号】TM914.42
  • 【下载频次】38
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