【摘要】 以4-羟基-2,2,6,6-四甲基哌啶氮氧自由基（ZJ-701）和丁酮为原料,质量分数30%的H₂O₂为氧化剂,CuCl为还原剂,通过自由基反应合成了1-乙氧基-4-羟基-2,2,6,6-四甲基哌啶醇,并通过红外光谱、核磁共振氢谱、核磁共振碳谱和质谱表征了其结构。结果表明,其较佳工艺条件为n（ZJ-701）∶n（丁酮）∶n（H₂O₂）∶n（CuCl）=1∶12∶5∶0.05,反应时间18h,反应温度30℃。在此条件下,产品的产率为56.5%,质量分数为98.91%。更多还原

【Abstract】 1-Ethoxy-2,2,6,6-tetramethylpiperidine-4-ol was synthesized through O-alkylation reaction by using 4-hydroxy-2,2,6,6-tetramethyl-piperidinooxy(（ZJ-701）and 2-butanone as raw materials,30%H₂ O₂ as oxidant,CuCl as reducing agent,and its structure was charateristized by IR,1 H NMR、13 C NMR and MS.The results revealed that its optimal conditions were as follows:n（ZJ-701）∶n（butanone）∶n（H₂ O₂）∶n（CuCl）=1∶12∶5∶0.05,the reaction time being 18 h,and the reaction temperature being 30℃.Under the above conditions,the yield of the products was 56.5%and the purity was 98.91%.更多还原