【摘要】 卟啉化学是有机化学研究中不可或缺的一个方向。由于卟啉在结构上具有一个大的共轭体系,从而具有典型的芳香性。其具有优异的光电性能、独特的光动力治疗作用、高效的催化活性,并且广泛存在于血红素、叶绿素、维生素B₁₂、过氧化氢酶等有机生物分子中,所有这一切都吸引着科学家们进行深入研究。本文从取代卟啉、缩合卟啉以及扩环卟啉三个方面分别讨论了卟啉的研究进展,通过列举一系列经典的反应以及卟啉衍生物,总结了卟啉衍生物的合成方法及其发展方向。另外,文中还对于卟啉的一些特殊物理、化学和光电性质,做了重点介绍。本文旨在为卟啉的研究者们提供参考。更多还原

【Abstract】 Porphyrin chemistry is an indispensable part of organic chemistry research. There are typical aromaticity as the porphyrins have a large conjugation system in structure. Porphyrins possess excellent photoelectric properties,unique photodynamic therapy effects,high catalytic activities,and presence in heme,chlorophyll,vitamin B₁₂,catalase and other organic biomolecules extensively,all of which are attractive to scientists in-depth study. In this article,we discussed the progress of porphyrins in three directions: substituted porphyrins,contracted porphyrins,and expanded porphyrins. The synthetic methods and development directions of porphyrin derivatives were summarized by citing a series of classical reactions and porphyrin derivatives. In addition,some special physical,chemical or photoelectric properties of porphyrins were also highlighted. The article is designed to provide a general reference for porphyrin researchers.更多还原