【摘要】 以2,6-二（2-苯并咪唑）吡啶（L）和2,2′-联吡啶（bpy）为混合配体,与五水硝酸镝反应利用缓慢挥发法合成了一个镝（Ⅲ）配合物[DyL₂（NO₃）₂]·bpy·CH₃OH·ClO₄（1）,并对其结构进行了X射线衍射表征、元素分析、红外和紫外光谱分析。配合物1属于三斜晶系,空间群P1。配位中心Dy（Ⅲ）通过丰富的超分子作用力构筑三维空间网络结构。由于配位原子的孤对电子参与大共轭π键与金属配位后使得配体荧光发射峰发生蓝移。更多还原

【Abstract】 A Dy（Ⅲ）complex,[DyL₂（NO₃）₂]·bpy·CH₃OH·ClO₄（1）,was synthesized by using 2,6-bis（benzimidazol-2-yl）pyridine（L）and 2,2′-dipyridine（bpy）as ligands and it was characterized by single crystal X-ray diffraction,element analysis,FI-IR and UV/Vis absorption spectra.The complex 1 belongs to triclinic system,space group P1.The coordinated centers are connected by abundant of hydrogen bonds into three-dimensional framework.The emission of complex1 blue-shifted compared to the ligand due to the lone pair electrons of coordinated atoms participating in the large conjugated aromatic structure.更多还原