【摘要】 制备了2,6-二氨基-3,5-二硝基吡嗪（ANPZ）纯度标准物质,采用红外（IR）、质谱（MS）、核磁共振（NMR）技术对其进行了结构表征。并使用¹H,¹³C,¹⁵N NMR技术,对其全部NMR信号进行了归属。结果表明,ANPZ分子与预测结构一致,其氨基偕位氢在¹H NMR中表现为2个单峰,化学位移分别为δ8.62,δ8.23;氨基碳、硝基碳的¹³CNMR化学位移分别为δ151.2,δ125.6;硝基、吡嗪环1位氮、吡嗪环4位氮、氨基的¹⁵N的化学位移分别为δ–13.95,δ–139.66,δ–74.43,δ–281.28。更多还原

【Abstract】 The purity reference material of 2,6-diamino-3,5-dinitropyrazine（ANPZ） was prepared, and its structure was characterized by infrared spectrum（IR）, mass spectrometry（MS） and nuclear magnetic resonance（NMR）. All NMR signals were assigned by ¹ H, ¹³C and ¹⁵N NMR technology. The results showed that ANPZ molecule was in accordance with the predicted structure, ¹ H NMR showed two single peaks at δ 8.62 and δ 8.23 which were assigned to amino group hydrogen, ¹³C NMR chemical shifts at δ 151.2 and δ 125.6 were assigned to the carbon atom attached to amino group and the carbon atom attached to nitro group, and ¹⁵N chemical shifts at δ –13.95, δ –139.66, δ –74.43, δ –281.28 were assigned to the nitrogen atoms of nitro, N1 in pyrazine ring, N4 in pyrazine ring and amino respectively.更多还原