Based on the validation of spiked soils recovery and optimization of analytical parameters,a gas chromatography mass spectrometry( GC-MS) equipped with a HP-5 MS column and selective ion monitoring( SIM) mode was developed for the determination of PAEs in soils. Differentiation ofgas chromatographic retention of PAEs was revealed at the same time. By combiming the quantum Hartree-Fock calculations of the major electronic structures and thermodynamic properties of PAEs,a quantitative structure-property relat...
Supported by National Key Research and Development Program of China(2016YFD0800204),National Natural Science Foundation of China(21377138),Frontier Project of Knowledge Innovation Engineering Field and“135”plans of CAS(ISSASIP1618) and Key Research Prog