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氨基化纳米Fe3O4的表征及其吸附机理研究

Study on characterization and adsorption mechanism of amination Fe3O4 nanoparticle

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【作者】 曾琪静王逸峰杨静任月明

【Author】 Zeng Qijing;Wang Yifeng;Yang Jing;Ren Yueming;Xinjiang Academy of Environmental Protection Science,Xinjiang Key Laboratory for Environmental Pollution Monitoring and Risk Warning;College of Material Science and Chemical Engineering,Key Laboratory of Superlight Materials and Surface Technology,Ministry of Education,Harbin Engineering University;

【机构】 新疆维吾尔自治区环境保护科学研究院新疆环境污染监控与风险预警重点实验室哈尔滨工程大学材料科学与化学工程学院超轻材料与表面技术教育部重点实验室

【摘要】 以二价铁盐和三价铁盐为原料,采用化学共沉淀法制备了磁性纳米四氧化三铁(Fe3O4),并采用3-氨基丙基-三甲氧基硅烷对其进行氨基化,制备出氨基化纳米Fe3O4。对氨基化纳米Fe3O4进行了表征及分析。研究结果表明:氨基已成功在纳米Fe3O4颗粒表面修饰,制得的氨基化纳米Fe3O4不含羟基铁等其他铁氧化物,改性后材料的磁性并没有发生明显变化。同时,研究了氨基化纳米Fe3O4吸附水中氟离子(F-)的动力学吸附机理,对F-的平衡吸附容量为4.7393mg/g,吸附符合动力学二级方程。

【Abstract】 Fe3O4 magnetic nanoparticles were prepared with the bivalent iron salt and trivalent iron salt as raw materials,and coprecipitation method.3-Aminopropyltrimethoxysilane was used to prepare amination Fe3O4 nanoparticle.Fe3O4 nanoparticles were characterized and analyzed.It was confirmed that the amino group was successfully modified on the surface of Fe3O4 nanoparticles,and the samples were free of other iron oxides such as hydroxyl iron.And the magnetism of material did not show great change after the modification.At the same time,the kinetic mechanism of adsorption of fluoride ions(F-)in ammoniated nano-Fe3O4 was studied.The equilibrium adsorption capacity of F-was 4.7393 mg/g,and the adsorption conformed to the kinetic second order equation.

【关键词】 纳米Fe3O4氨基化表征氟离子吸附机理
【Key words】 Fe3O4 nanoparticleaminationcharacterizationF-kinetic mechanism
【基金】 国家重点研发计划水资源高效开发利用专项(2016YFC0400505);国家重点研发计划“政府间国际科技创新合作”重点专项(2016YFE0123800);新疆维吾尔自治区公益性科研院所基本科研业务经费资助项目(KY2017125);新疆维吾尔自治区科技支疆项目(2016E02102)
  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2018年07期
  • 【分类号】O647.3;TB383.1
  • 【被引频次】6
  • 【下载频次】339
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