【摘要】 以十六烷基三甲基溴化铵为模板剂,正硅酸乙酯为硅源,MCM-41为载体,碱性条件下,合成Pd/Ni-MCM-41。通过XRD、HR-TEM、FT-IR和BET等对Pd/Ni-MCM-41进行表征。Pd/Ni-MCM-41的比表面积为（444.32～621.69） m²·g（-1）,孔容为（0.54～0.69） cm³·g^-1,孔径分布均匀,主要集中在（2～4） nm。将Pd/Ni-MCM-41用于苯甲醛加氢制备苯甲醇反应中,Ni质量分数6%时,在反应温度100℃和反应压力0.20 MPa条件下反应2 h,苯甲醛转化率65.1%,苯甲醇选择性为100%。更多还原

【Abstract】 Pd/Ni-MCM-41 was synthesized under alkaline conditions with cetyltrimethylammonium bromide as template,ethyl orthosilicate as silicon source and MCM-41 as carrier,and characterized by XRD,HR-TEM,FT-IR,BET and so on.Results showed that specific surface area of Pd/Ni-MCM-41 was（444.32-621.69） m²·g^-1,pore volume was（0.54-0.69） cm³·g^-1,and pore size was（2-4） nm.When Pd/Ni-MCM-41 with Ni mass fraction of 6% was used in hydrogenation of benzaldehyde to benzyl alcohol,conversion of benzaldehyde was 65.1% and selectivity was 100% in 2 h under 100 ℃ and 0.20 MPa.更多还原