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高性能钛酸锂/还原氧化石墨烯复合负极材料的合成与应用

Preparation and Application of High Performance Lithium Titanate/reduced Graphene Oxide Nanocomposites for Lithium Batteries

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【作者】 孙兵蒋尚王润伟倪玲裘式纶张宗弢

【Author】 SUN Bing;JIANG Shang;WANG Runwei;NI Ling;QIU Shilun;ZHANG Zongtao;College of Chemsitry,State Key Laboratory of Inorganic Synthesis & Preparative Chemistry,Jilin University;Institute of Carbon Materials Science,Datong University;

【通讯作者】 张宗弢;

【机构】 吉林大学化学学院无机合成与制备化学国家重点实验室大同大学碳材料研究所

【摘要】 通过简单的水热法制备了具有介孔结构的钛酸锂/还原氧化石墨烯(LTO/RGO)负极材料,并对该材料的结构及形貌进行了表征.结果表明,该方法获得的LTO/RGO负极材料具有高的比表面积且钛酸锂纳米片不易团聚.电化学性能测试结果表明,该材料在0. 1C倍率下的初始放电比容量达到182. 2 mA·h/g;在5C倍率下经过500周循环后容量仍保持在160. 6 mA·h/g,表现出较好的循环性能.

【Abstract】 Mesoporous lithium titanate/reduced graphene oxide anode material was synthesized by a simple hydrothermal method. The morphology and structure of the obtained materials were characterized. The electrochemical properties of the obtained materials were tested. The results show that the lithium titanate/reduced graphene oxide anode material posseses high specific surface area and the lithium titanate nanosheets are not easy to agglomerate; the initial discharge specific capacity is increased to 182. 2 mA ·h/g at 0. 1 C rate; and the cycling performance is greatly improved,with a cupacity of 160. 6 mA·h/g after 500 cycles at 5 C rate.

【基金】 国家自然科学基金(批准号:20841003,21261130584,20741001)资助~~
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2018年12期
  • 【分类号】TB332;TM912
  • 【被引频次】6
  • 【下载频次】305
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