An efficient heterogeneous catalyst, Pd@MIL-101(Cr)-NH_2, is prepared through a direct pathway of anionic exchange followed by hydrogen reduction with amino-containing MIL-101 as the host matrix. The composite is thermally stable up to 350℃ and the Pd nanoparticles uniformly disperse on the matal organic framework(MOF) support, which are attributed to the presence of the amino groups in the frameworks of MIL-101(Cr)-NH_2. The selective hydrogenation of biomass-based furfural to tetrahydrofurfuryl alcohol is...
【基金】
supported by the National Natural Science Foundation of China (21573031,21673032);
Program for Excellent Talents in Dalian City (2016RD09);
the Fundamental Research Funds for the Central Universities (DUT17LK21);
the State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University (201507)~~
【更新日期】
2018-03-06
【分类号】
O626.11
【正文快照】
1. Introduction stock for the sustainable production of biofuels and val‐ue‐added chemicals [3–6]. The catalytic hydrogenation of fur‐Recently, research efforts have been devoted to the produc‐fural has been extensively investigated, which can be tr
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