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粘多糖乳化降黏稠油的研究

Emulsification and viscosity reduction of heavy oil by mucopolysaccharides

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【作者】 王梦张鹏陈毅明张淑荣刘长霞谭天伟王芳刘春巧

【Author】 WANG Meng;ZHANG Peng;CHEN YiMing;ZHANG ShuRong;LIU ChangXia;TAN TianWei;WANG Fang;LIU ChunQiao;College of Life Science and Technology,Beijing University of Chemical Technology;

【机构】 北京化工大学生命科学与技术学院

【摘要】 利用本实验室生产的粘多糖A对辽河重质稠油进行乳化降黏试验,系统考察油水质量比、多糖浓度、乳化温度、乳化转速和乳化时间对稠油乳化降黏的影响。结果表明:将油水质量比6∶4,多糖质量浓度150 mg/L的稠油溶液放入温度25℃、转速160 r/min的摇床乳化6 h,稠油黏度由87000 m Pa·s降至310 m Pa·s,降黏率达到99.6%。此外,通过对乳化降黏后稠油破乳处理研究发现,稠油在室温静置24 h后即可实现油水分离,且破乳后的多糖水溶液可以重复使用2批次,显著降低了多糖乳化剂及后续稠油脱出水处理成本。因此,该粘多糖A可广泛应用于稠油乳化降黏开采和输送领域。

【Abstract】 The aim of the present study is to develop an efficient and cost-effective method for viscosity reduction of the heavy oil from the Liaohe oilfield by using mucopolysaccharide A as an emulsifier. The effects of varying the oilwater mass ratio,emulsifier concentration,emulsifying temperature,emulsifying agitation speed and emulsifying time on the emulsification and viscosity reduction were investigated. When a 6∶ 4 mass ratio of oil to water and 150 mg/L dosage of emulsifier were shaken at 25 ℃ at 160 r/min for 6 h,the viscosity of the heavy oil decreased from87000 m Pa·s to 310 m Pa·s,giving a viscosity reduction of 99. 6%. In addition,the separated water containing the polysaccharide essentially maintained its emulsifying and degreasing effect for two batches,indicating its potential for reducing the cost of emulsifier production and demulsifying treatment. These results suggest that mucopolysaccharide A can be widely used in the mining and transportation of heavy oil.

【基金】 教育部双一流建设专项经费(PY201616);国家自然科学基金(21406012);厦门市科学技术局产学研协同创新及科技合作项目(3502Z20172019)
  • 【文献出处】 北京化工大学学报(自然科学版) ,Journal of Beijing University of Chemical Technology(Natural Science Edition) , 编辑部邮箱 ,2018年02期
  • 【分类号】TE345
  • 【被引频次】2
  • 【下载频次】119
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