【摘要】 综述了3-氨基-4-偕氨肟基呋咱(AAOF)的几种典型合成方法;基于AAOF分子结构中氨基、偕氨肟基的反应活性,可合成3,4-双(4′-氨基呋咱-3′-基)氧化呋咱(DATF)、3,4-双(4′-硝基呋咱-3′-基)氧化呋咱(DNTF)、3,4-双(4′-叠氮基呋咱-3′-基)氧化呋咱(DAZTF)、呋咱胺含能化合物、呋咱醚(FOF-2、FOF-13、BFFO、TFO)等典型含能化合物。系统介绍了上述8大系列30种高含能化合物的合成技术途径及主要的物化性能,有望在高能炸药、高能推进剂等领域得到应用。附参考文献56篇。更多还原

【Abstract】 Several typical synthetic methods of 3-amino-4-aminoximiofurazan(AAOF)were reviewed.Based on the reaction activity of amino and amidoximo group in the AAOF,typical energetic compounds such as 3,4-bis(4′-aminofurazano-3′)furoxan(DATF),3,4-bis(4′-nitrofurazan-3′-yl)furoxan(DNTF),3,4-bis(4′-azidofurazano-3′-yl)furoxan(DAZTF),furazan amine energetic compounds and furazan ethers(FOF-2,FOF-13,BFFO,TFO)etc.can be synthesized.The synthetic technology and main physicochemical properties of the above eight series,thirty kinds of high energetic compounds,were systematically introduced and are expected to be applied in the fields of high energy explosives and high energy propellants.56 References are attached.更多还原