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Si含量对铁基高温合金抗氧化性能的影响

Effect of Si Content on Oxidation Resistance of Iron-Based Superalloy

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【作者】 刘杰潘晴川车畅刘俊友

【Author】 LIU Jie;PAN Qingchuan;CHE Chang;LIU Junyou;Boiler Department, China Special Equipment Inspection and Research Institute;School of Materials Science and Engineering, University of Science and Technology Beijing;

【机构】 中国特种设备检测研究院锅炉事业部北京科技大学材料学院

【摘要】 通过X射线衍射(XRD)、扫描电镜(SEM)及能谱分析(EDS)等手段对不同Si含量的铁基高温合金1 250℃下的抗氧化性能进行了研究。结果表明,1 250℃下,铁基高温合金抗氧化性能与Si含量的关系由优至劣的顺序是:0.93%Si>0%Si>2.76%Si>1.40%Si。含0.93%Si的铁基高温合金具有好的抗氧化性能的原因是,Si在基体与其致密的氧化膜之间形成了弥散分布的SiO2颗粒层,这些尺寸较小的SiO2颗粒与其氧化膜紧密连接犹如楔子般起着钉扎氧化膜的作用,改善了氧化膜的粘附性,进而提高了材料的抗氧化性能。

【Abstract】 The oxidation resistance of iron-based superalloy with different Si content at 1 250 ℃ was studied using XRD,SEM and EDS techniques. The results show that the sequence of oxidation resistance of the iron-based superalloys at 1 250 ℃ from superior to inferior is 0.93% Si > 0% Si > 2.76% Si > 1.40% Si. The reason for the outstanding oxidation resistance of iron-based superalloy with 0.93%Si is that dispersively distributed SiO2 particle layer is formed between the matrix and its compact oxide film. These small SiO2 particles join the oxide film closely and play a role of pinning as chocks, which improves the adhesion property of oxide film, and thus the oxidation resistance of the material is improved.

【基金】 国家重点研发计划资助项目(2016YFC0801904)
  • 【文献出处】 铸造技术 ,Foundry Technology , 编辑部邮箱 ,2017年07期
  • 【分类号】TG132.3
  • 【被引频次】6
  • 【下载频次】231
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