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Interactions between gas flow and reversible chemical reaction in porous media

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【作者】 姜元勇徐曾和张梦舟白立远

【Author】 JIANG Yuan-yong;XU Zeng-he;ZHANG Meng-zhou;BAI Li-yuan;School of Resources and Civil Engineering, Northeastern University;College of Applied Technology, Liaoning Technical University;Environmental Monitoring Center Station of Tangshan City;

【机构】 School of Resources and Civil Engineering, Northeastern UniversityCollege of Applied Technology, Liaoning Technical UniversityEnvironmental Monitoring Center Station of Tangshan City

【摘要】 Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.

【Abstract】 Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.

【基金】 Projects(51304035,50974030)supported by the National Natural Science Foundation of China;Project(20110491512)supported by the Postdoctoral Science Foundation of China;Project(20130042120034)supported by the Specialized Research Fund for the Doctoral Program of Higher Education(New Teachers),China;Project(120401008)supported by the Fundamental Research Funds for Central Universities,China;Project(L20150173)supported by the Scientific Research Fund of Liaoning Provincial Education Department,China
  • 【文献出处】 Journal of Central South University ,中南大学学报(英文版) , 编辑部邮箱 ,2017年05期
  • 【分类号】O643.19
  • 【被引频次】1
  • 【下载频次】41
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