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Synthesis and characterization of NaAlSi2O6 jadeite under 3.5 GPa

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【作者】 李刚王健李亚东陈宁陈良超郭龙锁赵亮苗辛原马红安贾晓鹏

【Author】 Gang Li;Jian Wang;Ya-Dong Li;Ning Chen;Liang-Chao Chen;Long-Suo Guo;Liang Zhao;Xin-Yuan Miao;Hong-An Ma;Xiao-Peng Jia;National Key Laboratory of Superhard Materials,Jilin University;

【机构】 National Key Laboratory of Superhard Materials,Jilin University

【摘要】 The high pressure and high temperature(HPHT) method is successfully used to synthesize jadeite in a temperature range of 1000℃–1400℃ under a pressure of 3.5 GPa. The initial raw materials are Na2SiO3·9H2O and Al2(SiO33.Through the HPHT method, the amorphous glass material is entirely converted into crystalline jadeite. We can obtain the good-quality jadeite by optimizing the reaction pressure and temperature. The measurements of x-ray diffraction(XRD),scanning electron microscopy(SEM), Fourier-transform infrared(FTIR) and Raman scattering indicate that the properties of synthesized jadeite at 1260℃ under 3.5 GPa are extremely similar to those of the natural jadeite. What is more, the results will be valuable for understanding the formation process of natural jadeite. This work also reveals the mechanism for metamorphism of magma in the earth.

【Abstract】 The high pressure and high temperature(HPHT) method is successfully used to synthesize jadeite in a temperature range of 1000℃–1400℃ under a pressure of 3.5 GPa. The initial raw materials are Na2SiO3·9H2O and Al2(SiO33.Through the HPHT method, the amorphous glass material is entirely converted into crystalline jadeite. We can obtain the good-quality jadeite by optimizing the reaction pressure and temperature. The measurements of x-ray diffraction(XRD),scanning electron microscopy(SEM), Fourier-transform infrared(FTIR) and Raman scattering indicate that the properties of synthesized jadeite at 1260℃ under 3.5 GPa are extremely similar to those of the natural jadeite. What is more, the results will be valuable for understanding the formation process of natural jadeite. This work also reveals the mechanism for metamorphism of magma in the earth.

【关键词】 synthetic jadeitestructural propertiesHPHT
【Key words】 synthetic jadeitestructural propertiesHPHT
【基金】 supported by the National Natural Science Foundation of China(Grant Nos.51172089 and 51171070);the Graduate Innovation Fund of Jilin University,China(Grant No.2016065)
  • 【文献出处】 Chinese Physics B ,中国物理B , 编辑部邮箱 ,2017年06期
  • 【分类号】TQ164
  • 【被引频次】2
  • 【下载频次】36
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