A mononuclear cobalt(Ⅱ) complex [Co(4-MeOC_6H_4Se)_2-(PMe_3)_3](1) and a dinuclear cobalt diphenylselenolato complex [Co(PMe_3)_2(SeC_6H_4-2-Me)]_2(2) were obtained from the reaction of 4-methoxyselenophenol and 2-methylselenophenol with Co(PMe_3)_4, respectively. The dicarbonyl cobalt(Ⅰ) complex [Co(PMe_3)_2(CO)_2(SeC_6H_4-2-Me)](3) was formed through the reaction of complex 2 with carbon monoxide. A novel selenophenolato hydridocobalt(III) complex [mer-Co(H)(SePh)_2(PMe_3)_3](4) and a dinuclear cobalt dip...
【基金】
国家自然科学基金(No.21372143)资助项目~~
【更新日期】
2017-07-27
【分类号】
O641.4
【正文快照】
*Corresponding author.E-mail:xli63@sdu.edu.cnReceived February 28,2017;revised April 14,2017;published online May 10,2017.Project supported by the National Natural Science Foundation of China(No.21372143).过渡金属氢化物是一类重要的金属有机化合物,被广泛应?
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