质子交换膜燃料电池(proton exchange membrane fuel cell,PEMFC)电堆由多个单电池串联叠加而成,材料、工艺和流场分布等因素可能引起单电池性能衰减,电堆运行寿命取决于电压最低的单体电池,电堆中单体电池电压均衡性是影响燃料电池寿命的重要因素.为了解决现有单体电压均衡性评价方法不能全面准确地反映燃料电池电压一致性的问题,探究电堆电流、流场分布和空间位置对单体电压波动率的影响,以14.4 k W PEMFC电堆测试平台为基础进行了单体电压均衡性实验研究.实验分别测试稳态时电堆电流以10 A为步长、从10 A加载到180 A和暂态时从47 A动态加载到112 A的单体电压波动率,加载策略采用恒频恒幅加载控制策略,负载加载的时间间隔为20 ms,电流加载幅值为2 A.首先,运用统计学掐头去尾的原则处理电堆稳态电流从10 A加载到180 A的数据,剔除端部单电池前(后)单体电压波动率与电流,分别得到Fourier 3项式和Gaussian2项式函数关系.然后,针对单体电压波动率无法分析电堆电压幅差和故障的缺点,提出将单体电压波动幅值、异众比率、最小距和电压平均差相结合的改进电压均衡性评价...
【英文摘要】
Proton exchange membrane fuel cell(PEMFC) stack is superimposed by multi single cells in series. Many factors such as material, process and flow field distribution may lead to the performance degradation of single cells. The service life of the stack depends on the single cell with thelowest voltage. Therefore,the single-cell voltage uniformity is an important factor affecting the fuel cell life. The existing voltage uniformity evaluation methods can not fully reflect the voltage consistency of fuel cells. ...