【摘要】 以合成具有荧光性能的配合物为目的,选用了三羧酸类有机配体3-（3-羧基-苯氧基）邻苯二甲酸（H3cppa）,与过渡金属Cd（Ⅱ）在水热145℃的条件下合成新颖结构的配合物[Cd（Hcppa）（H₂O）₂（CH₃OH）]_n.配合物通过X射线单晶衍射仪、TGA、FTIR、PXRD、荧光等对配合物的结构及性能进行了表征.分析表明:配位聚合物为一维链状结构,通过分子间弱作用力形成了三维网状结构,具有良好的热稳定性和荧光性能.更多还原

【Abstract】 In order to get with fluorescence property of coordination polymer.A coordination polymer based on a new tricarboxylate ligand 3-（3-carboxy-phenoxy）phthalic acid（H₃cppa）and cadmium（II）,namely [Cd（Hcppa）（H₂O）₂（CH₃OH）]_n,has been successfully synthesized via solvothermal reactions under the condition of 145 ℃.The coordination polymer forms a three dimensional（3D）supramolecular structure linked by intermolecular hydrogen bonds based on 1D chains.Additionally,the compounds had the good thermal stability property and the strong fluorescence,and characterized by X-ray single crystal diffraction,FTIR,PXRD,TGA and fluorescence.更多还原