Two novel silver complexes {[Ag(ttmb)(H_2O)]NO_3}n(1) and {[Ag(ttmb)]NO_3·H_2O}n(2) were synthesized by the reaction of AgNO_3 with 1,3,5-tri(1,2,4-triazol-1-ylmethyl)-2,4,6-trimethylbenzene(ttmb) in different solvents.The solid-state fluorescent properties of these two complexes and related ligand ttmb were then investigated at room temperature.Structural characterizations by elemental analysis,powder and single-crystal X-ray diffraction analysis and infrared spectra shows that complex 1 contains a highly ...
0 Introduction
In recent years,metal-organic frameworks(MOFs)have been rapidly developed and subjected to great attention,not only for their fantastic structures-cage,honeycomb,grid,ladder,multidimensional framework,polyrotaxane and polycatenane[1-5],but