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P与稀土复合变质对Al-20Si合金中Si相形貌的影响

Effects of P and Rare Earth Elements Compound Modification on the Morphology of Si Phase in Al-20Si Alloy

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【作者】 江峻廖福锦胡钟鹏王连登朱定一朱富斌

【Author】 Jiang Jun;Liao Fujin;Hu Zhongpeng;Wang Liandeng;Zhu Dingyi;Zhu Fubin;School of Materials Science and Engineering,Fuzhou University;School of Mechanical Engineering and Automation,Fuzhou University;Fujian Kinrui Hi-tech Co.,Ltd.;Institute of Semi-Solid Metal Technology(SSM),General Academy of Mechanical Science Research;

【机构】 福州大学材料科学与工程学院福州大学机械工程及自动化学院福建省金瑞高科有限公司机械科学研究总院(将乐)半固态技术研究所有限公司

【摘要】 以Al-20Si合金为研究对象,添加Cu-P和Al-RE中间合金对其进行变质处理,采用SEM扫描电镜、X射线衍射仪和光学金相显微镜分析变质处理对合金中Si相形貌的影响。结果表明,P与Al反应生成AlP化合物,可以作为初生Si相的异质形核质点,显著细化初生Si,稀土吸附固溶在Si相的生长台阶,使Al-20Si合金中Si相的晶格常数增大,X射线衍射图谱发生小角度偏移;随着变质时间延长,合金中板条状的初生Si变得细小圆润,平均晶粒尺寸由85.6μm减小至13.2μm,共晶Si由长针状转变为短杆状,弥散分布在基体中,硬度(HB)由68.5提升至80.8。

【Abstract】 Cu-P master alloy and Al-RE master alloy were added into Al-20 Si alloy to understand influence of modification treatment on microstructure of the alloy by SEM,X-ray diffractometer and optical metallographic microscope.The experimental results reveal that the AlP phase can be generated by reaction of P and Al as the heterogeneous nuclei of the primary silicon phase to effectively refine the primary silicon in the alloy.The rare earth elements are adsorbed and dissolved into the growth step of the Si phase,resulting in the increase of lattice constant of Si phase in the Al-20 Si alloy and the shift of X-ray diffraction pattern with a small angle.With the increase of modification time,the average grain size of primary silicon is decreased from 85.6μm to 13.2μm.The eutectic silicon phase is changed from long needle to short rod shape with uniform distribution in the matrix.The hardness(HB)is increased from68.5 to 80.8.

【基金】 福建省科技重大专项资助项目(2013HZ02090296);国家国际科技合作专项基金资助项目(2015DFA71350)
  • 【文献出处】 特种铸造及有色合金 ,Special Casting & Nonferrous Alloys , 编辑部邮箱 ,2017年12期
  • 【分类号】TG146.21
  • 【被引频次】11
  • 【下载频次】125
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