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某河道堆存尾砂重金属形态特征分布及风险评价

Morphological Distribution Analysis and Risk Assessment for Heavy Metals in Riverway Sand Tailings

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【作者】 盘樱李二平邱亚群何佳谢建平

【Author】 PAN Ying;LI Er-ping;QIU Ya-qun;HE Jia;XIE Jian-ping;School of Minerals Processing and Bioengineering,Central South University;Hunan Research Academy of Environmental Sciences;

【机构】 中南大学资源加工与生物工程学院湖南省环境保护科学研究院

【摘要】 以湖南省郴州市某河道堆存尾砂为研究对象,分析了尾砂中Cu、Pb、Zn、Mn和As等重金属的形态特征分布,并采用潜在生态危害指数法对河道尾砂重金属潜在生态风险进行了评价。结果显示,Pb、Zn、Cu、Mn和As生物可交换态含量分别为18.66%、6.77%、5.12%、5.00%和0.10%,说明Pb对生物的可利用性较高,给环境造成的潜在风险较大,其他4种元素对生物的可利用性较低,潜在风险较小。5种重金属潜在生态危害系数由高到低排列为:As>Pb>Cu>Mn>Zn,As元素为极强危害等级,Pb元素为很强危害等级,Cu元素为中等危害等级,Mn和Zn元素为轻微危害等级。从生态危害指数来看,As对生态危害指数的贡献最突出,其次是Pb,该河道具有很强的生态风险。

【Abstract】 With sand tailings heaps in some riverway in Chenzhou city of Hunan province as an example, the morphological distribution of heavy metals,including Cu,Pb,Zn,Mn and As,were analyzed,and potential ecological risk index method was used to assess the potential pollution of heavy metals to the ecology.Results show biological exchangeable states of five heavy metals of Pb,Zn,Cu,Mn and As are 18.66%,6.77%,5.12%,5.00% and 0.10%,respectively,indicating Pb could bring a greater potential risk on the environment due to its higher bioavailabilities,but a lesser potential risk for other four heavy metals.According to their potential ecological risk factors,those five heavy metals are ranked in the following descending order: As>Pb>Cu>Mn>Zn,indicating that As is of the highest hazardous grade,and high grade for Pb,medium grade for Cu,lower grade for Mn and Zn.In terms of ecological risk index,As makes the prominent contribution,followed by Pb,resulting in a higher ecological risk for this riverway.

【基金】 国家水体污染控制与治理科技重大专项(2010ZX07212-008);国家自然科学基金(51104189);中国博士后科学基金面上资助(2013M531814);中国博士后科学基金(2015T80880);中南大学博士后基金;稀贵金属综合利用新技术国家重点实验室开放课题(SKL-SPM-201508);粉末冶金国家重点实验室开放课题
  • 【文献出处】 矿冶工程 ,Mining and Metallurgical Engineering , 编辑部邮箱 ,2017年04期
  • 【分类号】X52;X820.4
  • 【下载频次】73
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