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5083铝合金表面镀钛/渗氮复合层组织结构与摩擦学性能
Microstructure and wear properties of duplex coatings fabricated by plasma nitriding of Ti-coated 5083 aluminum alloy
【摘要】 通过镀/渗复合改性方法在5083铝合金表面原位制备出梯度复合层,利用闭合场非平衡磁控溅射离子镀在5083铝合金表面沉积厚度约为6.0μm的Ti膜,然后将镀钛5083铝合金在490℃进行等离子渗氮8 h,研究了不同渗氮气氛(微量N,N-H比为0.05∶0.3,0.2∶0.3和0.3∶0.3)对复合层组织结构和力学性能的影响。结果表明:复合层由双层结构组成,即外层TiN0.3和靠近铝基体一侧的铝基金属化合物Al18Ti2Mg3,不同渗氮气氛下表层TiN0.3均出现(002)晶面择优生长,在N-H比为0.2∶0.3时,复合层的表面硬度高达880 HV,相比于未处理的基体铝合金硬度(98 HV)提高了约9倍。复合层的摩擦系数明显低于未处理态,并且磨损率显著降低。
【Abstract】 Duplex coatings were prepared on 5083 aluminum alloy surface by plasma nitriding. Firstly,Ti film with thickness of about 6. 0 μm was deposited on the surface of 5083 aluminum alloy by a closed field unbalanced magnetron sputtering equipment and then plasma nitrided at490 ℃ for 8 h,and effects of nitriding atmosphere on microstructure and mechanical properties of the coatings were investigated. The results show that the as-obtained coatings consist of two sub-layers,the outside TiN0.3layer and the inside Al18Ti2Mg3 layer. TiN0.3layers exhibit preferred(002) orientation under various nitriding atomsphere. The maximum surface hardness of 880 HV is achieved at the N-H ratio of0. 2∶ 0. 3,which is about 9 times of that of the untreated substrate. The duplex coatings exhibit low friction coefficient and wear rates.
【Key words】 5083 aluminum alloy; plasma nitriding; microstructure; wear;
- 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2017年03期
- 【分类号】TG174.4
- 【被引频次】1
- 【下载频次】276