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5083铝合金表面镀钛/渗氮复合层组织结构与摩擦学性能

Microstructure and wear properties of duplex coatings fabricated by plasma nitriding of Ti-coated 5083 aluminum alloy

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【作者】 章凡勇闫牧夫何继宁

【Author】 ZHANG Fan-yong;YAN Mu-fu;HE Ji-ning;National Key Laboratory for Precision Hot Processing of Metals,School of Materials Science and Engineering,Harbin Institute of Technology;Research Institute for Energy Equipment Materials,Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology,Hebei University of Technology;

【机构】 金属精密热加工国家级重点实验室哈尔滨工业大学材料科学与工程学院河北工业大学能源装备材料技术研究院天津市材料层状复合与界面控制技术重点实验室

【摘要】 通过镀/渗复合改性方法在5083铝合金表面原位制备出梯度复合层,利用闭合场非平衡磁控溅射离子镀在5083铝合金表面沉积厚度约为6.0μm的Ti膜,然后将镀钛5083铝合金在490℃进行等离子渗氮8 h,研究了不同渗氮气氛(微量N,N-H比为0.05∶0.3,0.2∶0.3和0.3∶0.3)对复合层组织结构和力学性能的影响。结果表明:复合层由双层结构组成,即外层TiN0.3和靠近铝基体一侧的铝基金属化合物Al18Ti2Mg3,不同渗氮气氛下表层TiN0.3均出现(002)晶面择优生长,在N-H比为0.2∶0.3时,复合层的表面硬度高达880 HV,相比于未处理的基体铝合金硬度(98 HV)提高了约9倍。复合层的摩擦系数明显低于未处理态,并且磨损率显著降低。

【Abstract】 Duplex coatings were prepared on 5083 aluminum alloy surface by plasma nitriding. Firstly,Ti film with thickness of about 6. 0 μm was deposited on the surface of 5083 aluminum alloy by a closed field unbalanced magnetron sputtering equipment and then plasma nitrided at490 ℃ for 8 h,and effects of nitriding atmosphere on microstructure and mechanical properties of the coatings were investigated. The results show that the as-obtained coatings consist of two sub-layers,the outside TiN0.3layer and the inside Al18Ti2Mg3 layer. TiN0.3layers exhibit preferred(002) orientation under various nitriding atomsphere. The maximum surface hardness of 880 HV is achieved at the N-H ratio of0. 2∶ 0. 3,which is about 9 times of that of the untreated substrate. The duplex coatings exhibit low friction coefficient and wear rates.

【基金】 国家自然科学基金(U1537201)
  • 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2017年03期
  • 【分类号】TG174.4
  • 【被引频次】1
  • 【下载频次】276
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