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银硫纳米簇合物的阴离子模板法合成、结构与发光性能
Synthesis,structures and luminescence of silver(Ⅰ) thiolate nanoclusters based on anion templates
【摘要】 银硫纳米簇合物的形成,因涉及多个组分的组装过程,其合成富有挑战性.而阴离子模板法是一种简单有效的合成银硫纳米簇合物的方法,特别是在对银硫纳米簇合物结构的控制方面表现出独特的优越性.结合本课题的工作,我们综述了简单的球形阴离子(如卤素离子、S2-等),三角形阴离子(如CO32-、NO3-等)及复杂的多酸阴离子(如[W6O21]6-、Mo6O228-等)为模板剂合成银硫纳米簇合物的研究进展,同时探索了合成的银硫纳米簇合物的结构和发光性能.
【Abstract】 The construction of silver(Ⅰ) thiolate nanoclusters is challenging because they involve the assembly of multiple components. Anionic template method is a simple and effective method for the synthesis of silver(Ⅰ) thiolate nanoclusters,especially for the control of their structures. In this mini review, we briefly summarizes the recent progress in the synthesis,crystal structures and luminescence of silver(Ⅰ) thiolate nanoclusters, which template by simple ball-like anions(halogen and S2-), trigonal anions(CO32-. and NO3-.), even complex POM anions([W6O21]6- and Mo6O228-). The size and type of anion templates play important roles in shaping the final silver(Ⅰ) thiolate nanoclusters.
【Key words】 silver thiolate nanoclusters; crystal structures; anion templates; luminescence;
- 【文献出处】 中国科学:化学 ,Scientia Sinica(Chimica) , 编辑部邮箱 ,2017年06期
- 【分类号】O641.4
- 【被引频次】5
- 【下载频次】283