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新型锐钛型晶种的制备和钛液水解研究

On Preparation of Anatase Type Seed Crystals and Investigation of Hydrolyzed Metatitanic Acid with TiO2 Crystals

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【作者】 陈满生邓奕芳张春华黄忆源李馥

【Author】 CHEN Man-sheng;DENG Yi-fang;ZHANG Chun-hua;HUANG Yi-yuan;LI Fu;College of Chemistry and Materials Science,Hengyang Normal University;Hunan Chuangda Yutu Chemical Co.Ltd.;

【机构】 衡阳师范学院化学与材料科学学院湖南创大玉兔化工有限公司

【摘要】 将二氧化钛溶于硫酸,过滤纯化,得到TiO2浓度为180~200g/L的钛液;将所述钛液缓慢加热至40~50℃后,加入到过量稀碱溶液中,在搅拌条件下,维持体系温度为40~50℃,调节酸度系数为0.27~0.3,进行水解反应,水解反应的终点pH控制在2.2~3.0,得到稳定性好,形貌均匀的高品质锐钛型晶种。晶种加量在1.5%~2%得到产品粒度适中,质量稳定。

【Abstract】 Firstly,Titania was dissolved in sulfuric acid,then filtering and purification,TiO2 concentration of titanium solution is180~200g/L.When the titanium liquid was slowly heated to 40~50 ℃,the excessive dilute alkali solution was added with stirring in temperature of 40~50 ℃,the acidity was adjusted in the range of 0.27~ 0.3.Finally,the hydrolysis reaction of pH in 2.2~3.0,the crystal has good stability,uniform morphology of high-quality anatase crystal.On the other hand,the influence of the quality with crystallizing amount and TiO2 concentration were also investigated.The experimental results exhibited that the amount of 1.5 %~2 % crystals is favorable for the production of stable production.

【关键词】 晶种制备水解
【Key words】 seed crystalpreparationhydrolysis
【基金】 湖南省自然科学基金衡阳市联合基金项目(2015JJ5004)
  • 【文献出处】 衡阳师范学院学报 ,Journal of Hengyang Normal University , 编辑部邮箱 ,2017年03期
  • 【分类号】TQ621.12
  • 【下载频次】113
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