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木质素电催化转化制取苯(英文)

Production of Benzene from Lignin through Current Enhanced Catalytic Conversion

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【作者】 吴小平范明慧李全新

【Author】 Xiao-ping Wu;Ming-hui Fan;Quan-xin Li;Department of Chemical Physics, Anhui Key Laboratory of Biomass Clean Energy, Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, University of Science and Technology of China;Anhui Key Laboratory of Tobacco Chemistry, China Tobacco Anhui Industrial Co., Ltd.;

【机构】 中国科学技术大学化学物理系安徽省生物质洁净能源重点实验室中国科学院城市污染物转化重点实验室安徽中烟工业有限责任公司技术中心

【摘要】 利用电流增强的木质素催化转化,实现了木质素定向合成苯的目标.该方法的主要特点是利用催化剂与电流的协同作用,促进了木质素的解聚和芳香族单体中官能团的选择性去除.结果表明,苯的选择性达到92.9%,苯的产率最高为每千克木质素生成175 g苯.

【Abstract】 The directional production of benzene is achieved by the current-enhanced catalytic conversion of lignin. The synergistic effect between catalyst and current promotes the depolymerization of lignin and the selective recombinant of the functional groups in the aromatic monomers. A high benzene yield of 175 gbenzene/kglignin was obtained with an excellent selectivity of 92.9 C-mol%. The process potentially provides a promising route for the production of basic petrochemical materials or high value-added chemicals using renewable biomass.

【基金】 supported by the National Natural SciTech Support Plan (No.2014BAD02B03);the Program for Changjiang Scholars and Innovative Research Team in University;the Fundamental Research Funds for the Central Universities (No.wk2060190040)
  • 【文献出处】 Chinese Journal of Chemical Physics ,化学物理学报(英文版) , 编辑部邮箱 ,2017年04期
  • 【分类号】TQ241.11
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