节点文献
木质素电催化转化制取苯(英文)
Production of Benzene from Lignin through Current Enhanced Catalytic Conversion
【摘要】 利用电流增强的木质素催化转化,实现了木质素定向合成苯的目标.该方法的主要特点是利用催化剂与电流的协同作用,促进了木质素的解聚和芳香族单体中官能团的选择性去除.结果表明,苯的选择性达到92.9%,苯的产率最高为每千克木质素生成175 g苯.
【Abstract】 The directional production of benzene is achieved by the current-enhanced catalytic conversion of lignin. The synergistic effect between catalyst and current promotes the depolymerization of lignin and the selective recombinant of the functional groups in the aromatic monomers. A high benzene yield of 175 gbenzene/kglignin was obtained with an excellent selectivity of 92.9 C-mol%. The process potentially provides a promising route for the production of basic petrochemical materials or high value-added chemicals using renewable biomass.
【关键词】 苯;
电流增强催化转化;
木质素;
分子筛;
【Key words】 Benzene; Current enhanced catalytic conversion; Lignin; Zeolite;
【Key words】 Benzene; Current enhanced catalytic conversion; Lignin; Zeolite;
【基金】 supported by the National Natural SciTech Support Plan (No.2014BAD02B03);the Program for Changjiang Scholars and Innovative Research Team in University;the Fundamental Research Funds for the Central Universities (No.wk2060190040)
- 【文献出处】 Chinese Journal of Chemical Physics ,化学物理学报(英文版) , 编辑部邮箱 ,2017年04期
- 【分类号】TQ241.11