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稀土LaNd对Zn9.3Al7Cu钎料腐蚀性能影响
Impact of rare earth LaNd on corrosion property of Zn9.3Al7Cu solder
【摘要】 采用合金化原理,在Zn9.3Al7Cu钎料基体中添加稀土LaNd,研究稀土LaNd对Zn9.3Al7Cu无铅钎料腐蚀性能的影响.结果表明,当LaNd添加量不超过0.3%时,随着LaNd添加量增加,Zn9.3Al7Cux LaNd钎料中弥散分布大量的耐蚀性较强的ε(CuZn5)相,钎料合金的腐蚀电位逐渐上升,抗腐蚀性增强;当LaNd添加量超过0.3%时,随着LaNd添加量增加,Zn9.3Al7Cux LaNd表面开始出现腐蚀坑,且腐蚀产物中O元素含量增加,钎料合金的腐蚀电位逐渐降低,耐腐蚀能力变弱.从Zn9.3Al7Cux LaNd钎料的腐蚀性能考虑,稀土LaNd的最佳添加量为0.3%.
【Abstract】 By using alloying principle,rare earth LaNd was added in the matrix Zn9.3Al7Cu solder to study the effects of La Nd on the corrosion resistance of Zn9. 3Al7Cu lead-free solder. The results showed that if the RE content was less than0. 3%,with the increase of RE content,the ε( CuZn5) phase which has strong corrosion resistance increased and dispersedly distributed,Zn9.3Al7CuxLaNd solder alloy corrosion potential increased,and then the corrosion resistance of solder increased.If the RE content was more than 0.3%,with the increase of RE content,some corrosion pits began to appear,the O content in corrosion products increased,Zn9.3Al7Cux La Nd solder alloy corrosion potential reduced,and then the corrosion rate of solder increased. 0. 3% is the best addition of La Nd standing on the point of corrosion resistance.
【Key words】 Zn9.3Al7CuxLaNd solder; corrosion potential; corrosion rate;
- 【文献出处】 焊接学报 ,Transactions of the China Welding Institution , 编辑部邮箱 ,2017年10期
- 【分类号】TG425
- 【被引频次】1
- 【下载频次】80