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三维石墨烯/聚噻吩杂化材料制备及室温气敏性能

Preparation and gas sensing property of three dimensional graphene/polythiophene nanocomposite

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【作者】 田俊峰尹志刚蒋登高

【Author】 Tian Junfeng;Yin zhigang;Jiang Denggao;School of Chemical Engineering and Energy,Zhengzhou University;Henan Provincial Key Laboratory of Surface & Interface Science,Zhengzhou University of Light Industry;

【机构】 郑州大学化工与能源学院郑州轻工业学院河南省表界面科学重点实验室

【摘要】 以三维石墨烯和噻吩为原料,利用化学氧化聚合法合成二元杂化材料三维石墨烯/聚噻吩(3D-rGO/PTh),噻吩单体在载体石墨烯片的表面发生聚合反应。杂化材料表征使用扫描电镜、红外光谱仪和比表面测试仪。结果表明,杂化材料有大量空隙,具有较大的比表面积。室温下,石墨烯质量含量7%时,复合物对NO2具有较好的气敏性能,NO2浓度10×10-6时,灵敏度达到34.1。复合材料气敏性能提高的原因在于大比表面积和协同效应。

【Abstract】 NO2 gas sensor based on three dimensional graphene/polythiophene(3D-rGO/PTh)hybrid was presented.PTh were anchored on the surface of 3D-rGO sheets by using 3D-rGO as templates.The developed hybrid was characterized by SEM,FT-IR and BET analysis.The NO2 gas sensing performance of hybrid was studied and compared with that of the sensor based on bare PTh.3D-rGO/PTh showed better response to NO2 gas than that of bare PTh.The sensitivity could reach 34.1for NO2 of 10×10-6.It shown that the synergetic behavior and large surface area allowed excellent sensitivity.

  • 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2017年06期
  • 【分类号】TB34
  • 【被引频次】1
  • 【下载频次】210
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