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三维石墨烯/聚噻吩杂化材料制备及室温气敏性能
Preparation and gas sensing property of three dimensional graphene/polythiophene nanocomposite
【摘要】 以三维石墨烯和噻吩为原料,利用化学氧化聚合法合成二元杂化材料三维石墨烯/聚噻吩(3D-rGO/PTh),噻吩单体在载体石墨烯片的表面发生聚合反应。杂化材料表征使用扫描电镜、红外光谱仪和比表面测试仪。结果表明,杂化材料有大量空隙,具有较大的比表面积。室温下,石墨烯质量含量7%时,复合物对NO2具有较好的气敏性能,NO2浓度10×10-6时,灵敏度达到34.1。复合材料气敏性能提高的原因在于大比表面积和协同效应。
【Abstract】 NO2 gas sensor based on three dimensional graphene/polythiophene(3D-rGO/PTh)hybrid was presented.PTh were anchored on the surface of 3D-rGO sheets by using 3D-rGO as templates.The developed hybrid was characterized by SEM,FT-IR and BET analysis.The NO2 gas sensing performance of hybrid was studied and compared with that of the sensor based on bare PTh.3D-rGO/PTh showed better response to NO2 gas than that of bare PTh.The sensitivity could reach 34.1for NO2 of 10×10-6.It shown that the synergetic behavior and large surface area allowed excellent sensitivity.
【Key words】 three dimensional graphene(3D-rGO); (polythiophene)PTh; gas sensing property; room temperature;
- 【文献出处】 化工新型材料 ,New Chemical Materials , 编辑部邮箱 ,2017年06期
- 【分类号】TB34
- 【被引频次】1
- 【下载频次】210